A series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation

被引：129

作者：

Yao, Qingxia ^{[1
]}

Sun, Junliang ^{[1
]}

Li, Kuo ^{[2
]}

Su, Jie ^{[1
]}

Peskov, Maxim V. ^{[1
]}

Zou, Xiaodong ^{[1
]}

机构：

[1] Stockholm Univ, Dept Mat & Environm Chem, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden

[2] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 14期

基金：

瑞典研究理事会;

关键词：

SORPTION PROPERTIES; HYDROGEN STORAGE; SURFACE-AREA; GAS-UPTAKE; COORDINATION; CATENATION; CATALYSIS; SITES; PORES; MOFS;

D O I：

10.1039/c2dt12088g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of metal-organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4',4 ''-benzene-1,3,5-triyl-benzoic acid (H3BTB) and 4,4'-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single-crystal transformation. This post-synthesis route can be used for synthesis of isomorphous metal-organic frameworks that cannot be obtained by direct synthesis.

引用

页码：3953 / 3955

页数：3

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