A series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation

被引：127
作者：
Yao, Qingxia [1 ]
Sun, Junliang [1 ]
Li, Kuo [2 ]
Su, Jie [1 ]
Peskov, Maxim V. [1 ]
Zou, Xiaodong [1 ]
机构：
[1] Stockholm Univ, Dept Mat & Environm Chem, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden
[2] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 14期
基金：
瑞典研究理事会;
关键词：
SORPTION PROPERTIES; HYDROGEN STORAGE; SURFACE-AREA; GAS-UPTAKE; COORDINATION; CATENATION; CATALYSIS; SITES; PORES; MOFS;
D O I：
10.1039/c2dt12088g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of metal-organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4',4 ''-benzene-1,3,5-triyl-benzoic acid (H3BTB) and 4,4'-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single-crystal transformation. This post-synthesis route can be used for synthesis of isomorphous metal-organic frameworks that cannot be obtained by direct synthesis.
引用
收藏
页码：3953 / 3955
页数：3
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