Phosphorus-Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry

被引：15
|
作者：
Ascherl, Johannes D. R. [1 ,3 ]
Neiss, Christian [2 ]
Vogel, Alexander [1 ,3 ]
Graf, Juergen [1 ]
Rominger, Frank [1 ]
Oeser, Thomas [1 ]
Hampel, Frank [4 ]
Goerling, Andreas [2 ]
Kivala, Milan [1 ,3 ]
机构：
[1] Heidelberg Univ, Inst Organ Chem, Neuenheimer Feld 270, D-69120 Heidelberg, Germany
[2] Friedrich Alexander Univ Erlangen Nurnberg, Dept Chem & Pharm, Chair Theoret Chem, Egerlandstr 3, D-91058 Erlangen, Germany
[3] Heidelberg Univ, Ctr Adv Mat, Neuenheimer Feld 225, D-69120 Heidelberg, Germany
[4] Univ Erlangen Nurnberg, Dept Chem & Pharm, Chair Organ Chem, Nikolaus Fiebiger Str 10, D-91058 Erlangen, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2020年 / 26卷 / 58期
关键词：
olefination; phosphorus heterocycles; photochemistry; polycyclic aromatic hydrocarbons; NEGATIVE HYPERCONJUGATION; ROUTE; REDUCTION; ACCEPTORS; DENSITY; DESIGN; BORON; OXIDE;
D O I：
10.1002/chem.202002872
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A concise synthetic route towards a new family of phosphorus-containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphorus center. X-ray crystallographic analysis, UV/Vis spectroscopic, and electrochemical studies supported by DFT calculations identified the considerable potential of these scaffolds for the development of organophosphorus functional materials with tailored properties upon further functionalization.
引用
收藏
页码：13157 / 13162
页数：6
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