Synthesis, reactions and applications of phosphorus containing carbon centered radicals

被引:3
作者
Balczewski, P [1 ]
Mikolajczyk, M [1 ]
Pietrzykowski, W [1 ]
机构
[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland
关键词
phosphonate; 1-diethoxyphophorylalkan-1-; -2-and-3-yl radicals; alkene; tri-n-butyltin hydride; methylenomycin B;
D O I
10.1080/10426509908039632
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A general method for synthesis of C-n-C (n = 1, 2...) phosphonate bonds involving a reaction of 1-diethoxy-phosphorylalkan-1-, -2-and -3-yl radicals; 1, 3, 6 with alkenes 4, a new example of functional group interconversion in I-heterosubstituted phosphonates and synthesis of useful phosphoroorganic compounds and methylenomycin B are described.
引用
收藏
页码:605 / 608
页数:4
相关论文
共 2 条
[1]   A new, effective approach for the C-C bond formation utilizing 1-, 2- and 3-phosphonyl substituted radicals derived from iodoalkylphosphonates and n-Bu3SnH/Et3B/O-2 system [J].
Balczewski, P ;
Pietrzykowski, WM .
TETRAHEDRON, 1997, 53 (21) :7291-7304
[2]  
BALCZEWSKI P, 1998, IN PRESS REV HETEROA