Two binuclear metallamacrocyclic zinc(II) coordination complexes derived from ferrocenecarboxylate and subsidiary ligands: synthesis, crystal structures and properties

被引：3
|
作者：
Liu, Yaru [1 ]
Cao, Zhenyu [2 ]
Hou, Hongwei [1 ]
Fan, Yaoting [1 ]
机构：
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China
[2] Donghua Univ, Text Inst, Shanghai 200051, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Sodium ferrocenecarboxylate; Subsidiary ligands; Binuclear metallamacrocyclic complexes; Electrochemical and luminescence properties; POLYMERS; CARBOXYLATE; FRAMEWORKS; BINDING; CLUSTER; CHAINS; SERIES; CO;
D O I：
10.1080/00958970802226379
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two binuclear zinc(II) coordination complexes, [Zn(FcCO2)2(prbbm)]2 2CH3OH 2H2O (1) (prbbm = 1,1'-(1,3-propanediyl)bis-1H-benzimidazole) and [Zn(FcCO2)2(pebbm)]2 4CH3OH (2) (pebbm = 1,1'-(1,5-pentanediyl)bis-1H-benzimidazole), were obtained by reaction of Zn(OAc)2 2H2O with sodium ferrocenecarboxylate (FcCOONa) and subsidiary ligands (prbbm or pebbm) in methanol. 1 and 2 are 0-D discrete macrocyclic frameworks with the ferrocenecarboxylate anions as monodentate ligands coordinating to Zn. Their electrochemical and luminescence properties were also investigated.
引用
收藏
页码：277 / 286
页数：10
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