Two binuclear metallamacrocyclic zinc(II) coordination complexes derived from ferrocenecarboxylate and subsidiary ligands: synthesis, crystal structures and properties

被引：3

作者：

Liu, Yaru ^{[1
]}

Cao, Zhenyu ^{[2
]}

Hou, Hongwei ^{[1
]}

Fan, Yaoting ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China

[2] Donghua Univ, Text Inst, Shanghai 200051, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Sodium ferrocenecarboxylate; Subsidiary ligands; Binuclear metallamacrocyclic complexes; Electrochemical and luminescence properties; POLYMERS; CARBOXYLATE; FRAMEWORKS; BINDING; CLUSTER; CHAINS; SERIES; CO;

D O I：

10.1080/00958970802226379

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two binuclear zinc(II) coordination complexes, [Zn(FcCO2)2(prbbm)]2 2CH3OH 2H2O (1) (prbbm = 1,1'-(1,3-propanediyl)bis-1H-benzimidazole) and [Zn(FcCO2)2(pebbm)]2 4CH3OH (2) (pebbm = 1,1'-(1,5-pentanediyl)bis-1H-benzimidazole), were obtained by reaction of Zn(OAc)2 2H2O with sodium ferrocenecarboxylate (FcCOONa) and subsidiary ligands (prbbm or pebbm) in methanol. 1 and 2 are 0-D discrete macrocyclic frameworks with the ferrocenecarboxylate anions as monodentate ligands coordinating to Zn. Their electrochemical and luminescence properties were also investigated.

引用

页码：277 / 286

页数：10

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