The role of reticular chemistry in the design of CO2 reduction catalysts

被引:620
作者
Diercks, Christian S. [1 ,2 ,3 ]
Liu, Yuzhong [1 ,2 ,3 ]
Cordova, Kyle E. [1 ,2 ,3 ,4 ]
Yaghi, Omar M. [1 ,2 ,3 ,4 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Kavli Energy NanoSci Inst Berkeley, Berkeley, CA USA
[3] Univ Calif Berkeley, Berkeley Global Sci Inst, Berkeley, CA 94720 USA
[4] King Fahd Univ Petr & Minerals, Ctr Res Excellence Nanotechnol, Dhahran, Saudi Arabia
关键词
METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE REDUCTION; VISIBLE-LIGHT; ELECTROCHEMICAL REDUCTION; ARTIFICIAL PHOTOSYNTHESIS; INORGANIC SEMICONDUCTOR; WATER; PHOTOCATALYSIS; CONDUCTIVITY; CONVERSION;
D O I
10.1038/s41563-018-0033-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The problem with current state-of-the-art catalysts for CO2 photo-or electroreduction is rooted in the notion that no single system can independently control, and thus optimize, the interplay between activity, selectivity and efficiency. At its core, reticular chemistry is recognized for its ability to control, with atomic precision, the chemical and structural features (activity and selectivity) as well as the output optoelectronic properties (efficiency) of porous, crystalline materials. The molecular building blocks that are in a reticular chemist's toolbox are chosen in such a way that the structures are rationally designed, framework chemistry is performed to integrate catalytically active components, and the manner in which these building blocks are connected endows the material with the desired optoelectronic properties. The fact that these aspects can be fine-tuned independently lends credence to the prospect of reticular chemistry contributing to the design of next-generation CO2 reduction catalysts.
引用
收藏
页码:301 / 307
页数:7
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