Nonlinear photooxidation of diamond surface exposed to femtosecond laser pulses

被引:18
作者
Kononenko, V. V. [1 ,2 ]
Gololobov, V. M. [1 ]
Komlenok, M. S. [1 ,2 ]
Konov, V. I. [1 ,2 ]
机构
[1] RAS, Inst Gen Phys, Moscow 119991, Russia
[2] Natl Res Nucl Univ, MEPhI Moscow Engn Phys Inst, Moscow 115409, Russia
关键词
femtosecond radiation; diamond; laser-induced chemistry; OXYGEN; PICOSECOND; DESORPTION; ABLATION; DYNAMICS; NM;
D O I
10.1088/1612-2011/12/9/096101
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We present an experimental investigation of photooxidation of a diamond surface exposed to femtosecond laser pulses that induce transient high concentrations of free carriers (>10(22)cm(-3)) while the lattice stays cold. Etching rate measurements and a laser-induced plasma study indicated that the rate of desorption of carbon species is proportional to the square of the induced plasma density, which contrasts with previous investigations of diamond etching by nanosecond pulses. We discuss how laser-induced ionization of diamond occurs and how it affects the photoreaction mechanism.
引用
收藏
页数:5
相关论文
共 18 条
[1]   THE KINETICS OF CHEMICAL-VAPOR-DEPOSITED DIAMOND-OXYGEN REACTION [J].
ALAM, M ;
SUN, Q .
JOURNAL OF MATERIALS RESEARCH, 1993, 8 (11) :2870-2878
[2]   MNDO ANALYSIS OF THE OXIDIZED DIAMOND(100) SURFACE [J].
BADZIAG, P ;
VERWOERD, WS .
SURFACE SCIENCE, 1987, 183 (03) :469-483
[3]   Nanostructuring and oxidation of diamond by two-photon ultraviolet surface excitation: An XPS and NEXAFS study [J].
Baldwin, C. G. ;
Downes, J. E. ;
McMahon, C. J. ;
Bradac, C. ;
Mildren, R. P. .
PHYSICAL REVIEW B, 2014, 89 (19)
[4]   Molecular oxygen adsorption and desorption from single crystal diamond (111) and (110) surfaces [J].
Bobrov, K ;
Schechter, H ;
Hoffman, A ;
Folman, M .
APPLIED SURFACE SCIENCE, 2002, 196 (1-4) :173-180
[5]  
Chichkov BN, 1996, APPL PHYS A-MATER, V63, P109, DOI 10.1007/BF01567637
[6]   A surface topographic investigation of {001} diamond surfaces etched in oxygen [J].
de Theije, FK ;
van der Laag, NJ ;
Plomp, M ;
van Enckevort, WJP .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 2000, 80 (03) :725-745
[7]  
Evans T., 1962, P 5 C CARB PERG, P147, DOI 10.1016/B978-0-08-009707-7.50025-X
[8]   ACTIVATION-ENERGY AND MECHANISM OF CO DESORPTION FROM (100) DIAMOND SURFACE [J].
FRENKLACH, M ;
HUANG, D ;
THOMAS, RE ;
RUDDER, RA ;
MARKUNAS, RJ .
APPLIED PHYSICS LETTERS, 1993, 63 (22) :3090-3092
[9]   Photoinduced laser etching of a diamond surface [J].
Kononenko, V. V. ;
Komlenok, M. S. ;
Pimenov, S. M. ;
Konov, V. I. .
QUANTUM ELECTRONICS, 2007, 37 (11) :1043-1046
[10]   Laser-induced modification of bulk fused silica by femtosecond pulses [J].
Kononenko, V. V. ;
Pashinin, V. P. ;
Komlenok, M. S. ;
Konov, V. I. .
LASER PHYSICS, 2009, 19 (06) :1294-1299