The first substituted macrocyclic ligand Py2N4S2 containing four naphthylmethylene pendant-armed groups: Synthesis and photophysical properties

被引：4

作者：

Garcia, Veronica ^{[1
]}

Aldrey, Anxela ^{[1
]}

De Castro, Catherine S. ^{[2
]}

Bastida, Rufina ^{[1
]}

Macias, Alejandro ^{[1
]}

Lodeiro, Carlos ^{[3
]}

Sergio Seixas de Melo, J. ^{[2
]}

Nunez, Cristina ^{[3
,4
]}

机构：

[1] Univ Santiago de Compostela, Dept Inorgan Chem, Fac Chem, Santiago De Compostela 15782, Spain

[2] Univ Coimbra, Dept Chem, P-3004535 Coimbra, Portugal

[3] Univ Nova Lisboa, BIOSCOPE Grp, REQUIMTE CQFC, Chem Dept,FCT UNL, P-2829516 Monte De Caparica, Portugal

[4] Canterbury Christ Church Univ, Ecol Res Grp, Dept Geog & Life Sci, Canterbury CT1 1QU, Kent, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 36卷

关键词：

Macrocycles; Dinuclear complex; Stability constant; Naphthalene; Pendant-arms; Sensor; METAL-ION BINDING; LARIAT AZA-CROWN; SCHIFF-BASES; KINETIC-DATA; DONOR ATOMS; COMPLEXES; CATIONS; CHEMISTRY; PYRIDINE; ANIONS;

D O I：

10.1016/j.inoche.2013.07.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a pendant donor emissive macrocyclic ligand Py2N4S2 with up to four naphthylmethylene arms (L) has been achieved. Their derivative solid metal complexes (Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Ag+) have been isolated and characterized. The photophysical properties of the free ligand L and their complexation behaviour have been investigated in solution. In dichloromethane, the free ligand presents two emission bands which are related to the monomer naphthalene emission and a red-shifted band attributable to ground state dimers (interaction between two naphthalene chromophores), which was further validated from time-resolved data, with bi-exponential decay with absence of dynamic components. UV-Vis spectroscopy has revealed a 2:1 binding stoichiometry for Co2+, Cu2+, Zn2+, Hg2+ and Ag+. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：22 / 26

页数：5

共 34 条

[1] Intramolecular excimer formation in a tripodal polyamine receptor containing three naphthalene fluorophores [J].

Albelda, MT ;

García-España, E ;

Gil, L ;

Lima, JC ;

Lodeiro, C ;

de Melo, JS ;

Melo, MJ ;

Parola, AJ ;

Pina, F ;

Soriano, C .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (27) :6573-6578

[2] Metal-free methods in the synthesis of macrocyclic Schiff bases [J].

Borisova, Nataliya E. ;

Reshetova, Marina D. ;

Ustynyuk, Yuri A. .

CHEMICAL REVIEWS, 2007, 107 (01) :46-79

[3] Specific interaction of citrate with bis(fluorophoric) bibrachial lariat aza-crown in comparison with the other components of the Krebs cycle [J].

Clares, M. Paz ;

Lodeiro, Carlos ;

Fernandez, Damian ;

Parola, A. Jorge ;

Pina, Fernando ;

Garcia-Espana, Enrique ;

Soriano, Conxa ;

Tejero, Roberto .

CHEMICAL COMMUNICATIONS, 2006, (36) :3824-3826

[4] Synthesis and H+, Cu2+, and Zn2+ coordination behavior of a bis(fluorophoric) bibrachial lariat aza-crown [J].

Clares, MP ;

Aguilar, J ;

Aucejo, R ;

Lodeiro, C ;

Albelda, MT ;

Pina, F ;

Lima, JC ;

Parola, AJ ;

Pina, J ;

de Melo, JS ;

Soriano, C ;

García-España, E .

INORGANIC CHEMISTRY, 2004, 43 (19) :6114-6122

[5] Fit and misfit between ligands and metal ions [J].

Comba, P ;

Schiek, W .

COORDINATION CHEMISTRY REVIEWS, 2003, 238 :21-29

[6] Energetics and dynamics of naphthalene polyaminic derivatives.: Influence of structural design in the balance static vs dynamic excimer formation [J].

de Melo, JS ;

Pina, J ;

Pina, F ;

Lodeiro, C ;

Parola, AJ ;

Lima, JC ;

Albelda, MT ;

Clares, MP ;

Garcia-España, E ;

Soriano, C .

JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (51) :11307-11318

[7] Direct visual indication of pH windows: 'Off-on-off' fluorescent PET (photoinduced electron transfer) sensors switches [J].

de Silva, AP ;

Gunaratne, HQN ;

McCoy, CP .

CHEMICAL COMMUNICATIONS, 1996, (21) :2399-2400

[8] A fluorescent photoinduced electron transfer sensor for cations with an off-on-off proton switch [J].

deSilva, SA ;

Zavaleta, A ;

Baron, DE ;

Allam, O ;

Isidor, EV ;

Kashimura, N ;

Percarpio, JM .

TETRAHEDRON LETTERS, 1997, 38 (13) :2237-2240

[9] A fluorescent molecular thermometer based on the nickel(II) high-spin/low-spin interconversion [J].

Engeser, M ;

Fabbrizzi, L ;

Licchelli, M ;

Sacchi, D .

CHEMICAL COMMUNICATIONS, 1999, (13) :1191-1192

[10] Metallobiosites and their synthetic analogues - a belief in synergism - 1997-1998 Tilden Lecture [J].

Fenton, DE .

CHEMICAL SOCIETY REVIEWS, 1999, 28 (03) :159-168

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