Syntheses, structures and characterisation of two CuII polymers with 8-connected topologies based on highly connected SBUs

被引：51

作者：

Zhang, Jian ^{[1
]}

Kang, Yao ^{[1
]}

Zhang, Jie ^{[1
]}

Li, Zhao-Ji ^{[1
]}

Qin, Ye-Yan ^{[1
]}

Yao, Yuan-Gen ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 11卷 / 11期

关键词：

coordination polymers; copper; hydrothermal synthesis; magnetic properties; N ligands;

D O I：

10.1002/ejic.200500904

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two hydrothermally synthesised 3D metal-coordination polymers, namely [Cu(isonicotinate)(nicotinate)], (1), with an 8-connected CsCl topology, and [Cu-2(mu(3)-OH)(isonicotinate)(2)(BDC)(0.5)](n) (2), with an unusual 8-connected 3(5).4(11).5(8).6(4) topology, demonstrate that highly connected SBUs can be employed in the construction of complicated frameworks. The temperature-dependent magnetic susceptibilities for the two complexes were also determined. (c) Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2253 / 2258

页数：6

共 27 条

[21] An unprecedented eight-connected self-penetrating network based on pentanuclear zinc cluster building blocks [J].