Anionic amido/carbocyclic carbene ligated palladium (II) complex for room temperature Suzuki reaction

被引：9

作者：

Kantam, M. Lakshmi ^{[1
]}

Parsharamulu, T. ^{[1
]}

Likhar, Pravin R. ^{[1
]}

Srinivas, P. ^{[1
]}

机构：

[1] Indian Inst Chem Technol, I & PC Div, Hyderabad 500607, Andhra Pradesh, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 729卷

关键词：

Suzuki reaction; Carbocyclic carbene; Phosphine-free; Palladium; Room temperature; LOW-SPIN IRON(III); CARBOCYCLIC CARBENE; CATALYST SYSTEM; N COORDINATION; C-C; EFFICIENT; LIGAND; PALLADACYCLES; CARBON; IRON;

D O I：

10.1016/j.jorganchem.2013.01.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of anionic amido/carbocyclic carbene ligated Pd (II) complex has been reported. The palladium complex is an active catalyst for the cross-coupling reaction between aryl bromides and phenylboronic acids under phosphine-free conditions at room temperature. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：9 / 13

页数：5

共 36 条

[1] Looking for stable carbenes: The difficulty in starting anew [J].

Arduengo, AJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) :913-921

[2] Application of the palladium-catalyzed borylation/Suzuki coupling (BSC) reaction to the synthesis of biologically active biaryl lactams [J].

Baudoin, O ;

Cesario, M ;

Guénard, D ;

Guéritte, F .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (04) :1199-1207

[3] The development of palladium catalysts for C-C and C-heteroatom bond forming reactions of aryl chloride substrates [J].

Bedford, RB ;

Cazin, CSJ ;

Holder, D .

COORDINATION CHEMISTRY REVIEWS, 2004, 248 (21-24) :2283-2321

[4] Stable carbenes [J].

Bourissou, D ;

Guerret, O ;

Gabbaï, FP ;

Bertrand, G .

CHEMICAL REVIEWS, 2000, 100 (01) :39-91

[5] Alfred Werner revisited: The coordination chemistry of anions [J].

Bowman-James, K .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) :671-678

[6] OXIDATIVE ADDITION OF CARBON OXYGEN AND CARBON NITROGEN DOUBLE-BONDS TO WCL2(PMEPH2)4 - SYNTHESIS OF TUNGSTEN METALLAOXIRANE AND TUNGSTEN OXO-ALKYLIDENE AND IMIDO ALKYLIDENE COMPLEXES [J].

BRYAN, JC ;

MAYER, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) :2298-2308

[7]

Collman J.P., 1987, PRINCIPLES APPL ORGA

[8]

Deng YJ, 2003, SYNTHESIS-STUTTGART, P337

[9]

Diederich F., 1998, Metal-Catalyzed Cross-Coupling Reactions

[10] Multikilogram-scale synthesis at a biphenyl carboxylic acid derivative using a Pd/C-mediated Suzuki coupling approach [J].

Ennis, DS ;

McManus, J ;

Wood-Kaczmar, W ;

Richardson, J ;

Smith, GE ;

Carstairs, A .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1999, 3 (04) :248-252

← 1 2 3 4 →