Two-Photon Excitation Behavior of Thiophene-Based Oligomers and a Polymer

被引:3
|
作者
Yamamoto, Takakazu [1 ]
Kumagai, Akira [1 ]
Saito, Kenta [2 ]
Nagai, Takeharu [2 ]
机构
[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0010020, Japan
关键词
alpha-Conjugated Polymer; Oligomer; Two-Photone Excitation; CROSS-SECTIONS; ABSORPTION; SPECTRUM;
D O I
10.1166/jnn.2009.J070
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The two-photon excitation action cross-sections of four kinds of co-oligomers of thiophene and pyridine (e.g., Py-(Th)(n)-Py; Py = 2-pyridyl, Th = thiophene-2,5-diyl; n = 3, 4) and a copolymer constituted of alternating pyridazine and 4,4'-dihexyl- 2,2'-bithiophene units have been measured by using a reported value ((sigma(2PE) at 780 nm = 10 GM) of green fluorescent protein as the reference. The co-oligomers give sigma(2PE) values of 14-26 GM and the copolymer shows sigma(2PE) of 23 GM.
引用
收藏
页码:670 / 672
页数:3
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