Modified silica-based isoprene rubber composite by a multi -functional silane: Preparation and its mechanical and dynamic mechanical properties

被引:31
作者
Wang, Xuefei [1 ,2 ]
Wu, Lingling [2 ]
Yu, Haiwen [2 ]
Xiao, Tongliang [2 ]
Li, Huaming [1 ]
Yang, Jun [1 ,2 ]
机构
[1] Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China
[2] Zhuzhou Times New Mat Technol Co Ltd, Zhuzhou 412007, Hunan, Peoples R China
关键词
Multi-functional silane; Silica-based isoprene rubber composite; Dispersion; Mechanical properties; Dynamic mechanical properties; FILLER-ELASTOMER INTERACTIONS; EPOXIDIZED NATURAL-RUBBER; COUPLING AGENTS; SURFACE MODIFICATION; NANOCOMPOSITES; NANOPARTICLES; PARTICLES; TIME;
D O I
10.1016/j.polymertesting.2020.106840
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Modified silica-based isoprene rubber (IR) composite has been designed and prepared by using a multi-functional silane, 2-aminoethyl 2-(3-triethoxysilylpropyl)aminoethyl disulfide (ATD), as coupling agent. Such modification significantly improved the dispersity of silica in the corresponding composites, as verified by SEM observation. And the hardness, tensile strength, stress at definite elongation, tear strength and temperature rise as well as the value of dynamic loss coefficient ranging from 0 degrees C to 80 degrees C of silica/IR vulcanized composites, are significantly improved, especially with low ATD dosage (2-4 phr). This modification of silica-based IR composite by employing ATD as coupling agent provides a facile and effective method to prepare silica-based rubber composites with improved mechanical properties and low hysteresis.
引用
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页数:10
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