Ruthenium Trichloride Catalyzed Highly Efficient Deoximation of Oximes to the Carbonyl Compounds and Nitriles without Acceptors

被引：17
|
作者：
Liu, Yuxiao [1 ]
Yang, Na [1 ]
Chu, Changhu [1 ]
Liu, Renhua [1 ]
机构：
[1] E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2015年 / 33卷 / 09期
基金：
中国国家自然科学基金; 国家高技术研究发展计划(863计划);
关键词：
deoximation; ruthenium trichloride; hydrolysis; acceptor-free; MILD CONDITIONS; BECKMANN REARRANGEMENT; AQUEOUS-MEDIUM; SILICA-GEL; C=N BONDS; REGENERATION; KETONES; ACID; DEPROTECTION; CONVERSION;
D O I：
10.1002/cjoc.201500325
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An acceptor-free catalysis protocol for the deoximation of ketoximes and aldoximes using RuCl3 as the catalyst has been developed. Under the optimized conditions, various oximes were converted to ketones and nitriles with excellent isolated yields.
引用
收藏
页码：1011 / 1014
页数：4
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