A Convenient Synthesis of (S)-H4-BINOL and Its Derivatives via Hydrogenation of Monoesters of BINOL

被引：3
|
作者：
Li, Xinsheng [1 ]
Ding, Qianchang [1 ]
Ge, Jianfeng [2 ]
Xie, Jianwu [1 ]
Xu, Dongcheng [1 ]
机构：
[1] Zhejiang Normal Univ, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China
[2] Suzhou Univ, Dept Mat & Engn, Suzhou 215006, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 04期
关键词：
DIELS-ALDER REACTION; ENANTIOSELECTIVE ADDITION; ASYMMETRIC CATALYSIS; AROMATIC-ALDEHYDES; 1,1'-BINAPHTHYLS; REDUCTION; LIGANDS; 5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL; DIETHYLZINC; COMPLEXES;
D O I：
10.1021/jo802542m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new multigram synthesis of chiral (S)-H-4-BINOL and its derivatives in moderate to high yield (up to 83% total yield) via monoesterification of (S)-BINOL, hydrogenation, and saponification reaction was described. The two new monomethylated (S)-H-4-BINOL obtained may be useful materials in asymmetric catalysis.
引用
收藏
页码：1785 / 1787
页数：3
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