A Convenient Synthesis of (S)-H4-BINOL and Its Derivatives via Hydrogenation of Monoesters of BINOL

被引：4

作者：

Li, Xinsheng ^{[1
]}

Ding, Qianchang ^{[1
]}

Ge, Jianfeng ^{[2
]}

Xie, Jianwu ^{[1
]}

Xu, Dongcheng ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China

[2] Suzhou Univ, Dept Mat & Engn, Suzhou 215006, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 04期

关键词：

DIELS-ALDER REACTION; ENANTIOSELECTIVE ADDITION; ASYMMETRIC CATALYSIS; AROMATIC-ALDEHYDES; 1,1'-BINAPHTHYLS; REDUCTION; LIGANDS; 5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL; DIETHYLZINC; COMPLEXES;

D O I：

10.1021/jo802542m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new multigram synthesis of chiral (S)-H-4-BINOL and its derivatives in moderate to high yield (up to 83% total yield) via monoesterification of (S)-BINOL, hydrogenation, and saponification reaction was described. The two new monomethylated (S)-H-4-BINOL obtained may be useful materials in asymmetric catalysis.

引用

页码：1785 / 1787

页数：3

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