Production of bio-oil and biochar from soapstock via microwave-assisted co-catalytic fast pyrolysis

被引:86
作者
Dai, Leilei [1 ,2 ]
Fan, Liangliang [1 ,2 ,3 ,4 ]
Liu, Yuhuan [1 ,2 ]
Ruan, Roger [1 ,2 ,3 ,4 ]
Wang, Yunpu [1 ,2 ]
Zhou, Yue [1 ,2 ]
Zhao, Yunfeng [1 ,2 ]
Yu, Zhenting [1 ,2 ]
机构
[1] Nanchang Univ, Engn Res Ctr Biomass Convers, Minist Educ, Nanchang 330047, Jiangxi, Peoples R China
[2] Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Jiangxi, Peoples R China
[3] Univ Minnesota, Ctr Biorefining, 1390 Eckles Ave, St Paul, MN 55108 USA
[4] Univ Minnesota, Dept Bioprod & Biosyst Engn, 1390 Eckles Ave, St Paul, MN 55108 USA
基金
中国国家自然科学基金;
关键词
Microwave; Catalytic fast pyrolysis; Bentonite; HZSM-5; Bio-oil; Bio-char; BIOMASS; GASOLINE; SAWDUST; SLUDGE; HZSM-5; WASTE; VAPOR;
D O I
10.1016/j.biortech.2016.11.017
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In this study, production of bio-oil and biochar from soapstock via microwave-assisted co-catalytic fast pyrolysis combining the advantages of in-situ and ex-situ catalysis was performed. The effects of catalyst and pyrolysis temperature on product fractional yields and bio-oil chemical compositions were investigated. From the perspective of bio-oil yield, the optimal pyrolysis temperature was 550 degrees C. The use of catalysts reduced the water content, and the addition of bentonite increased the bio-oil yield. Up to 84.16 wt.% selectivity of hydrocarbons in the bio-oil was obtained in the co-catalytic process. In addition, the co-catalytic process can reduce the proportion of oxygenates in the bio-oil to 15.84 wt.% and eliminate the N-containing compounds completely. The addition of bentonite enhanced the BET surface area of bio-char. In addition, the bio-char removal efficiency of Cd2+ from soapstock pyrolysis in presence of bentonite was 27.4 wt.% higher than without bentonite. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1 / 8
页数:8
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