The oxidant peroxo method (OPM) as a new alternative for the synthesis of lead-based and bismuth-based oxides

被引:20
作者
Camargo, Emerson R. [1 ]
Dancini, Mayra Goncalves [1 ]
Kakihana, Masasto [2 ]
机构
[1] UFSCar Fed Univ Sao Carlos, Dept Chem, Interdisciplinary Lab Electrochem & Ceram, BR-13565905 Sao Carlos, SP, Brazil
[2] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
基金
巴西圣保罗研究基金会;
关键词
powder processing; chemical synthesis; ceramic; SOL-GEL PREPARATION; TITANATE; POWDERS; FILMS; EVOLUTION; TITANIUM; HALIDES; ROUTE;
D O I
10.1557/jmr.2013.288
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The oxidant peroxo method (OPM) exhibits several advantage and unique characteristics not found in the traditional methods for the synthesis of lead- and bismuth-based oxides. First of all, it is a clean method based on hydrogen peroxide that matches perfectly with the green chemistry approach. Second, the oxidizing local atmosphere provided by the precursor during its crystallization is unique among all the wet chemical techniques of synthesis, which usually result in reducing environment. Besides these advantages, only a few studies have focused on the use of the OPM to obtain better materials, which makes this field of study an excellent opportunity for the development of materials with higher purity and controlled morphologies.
引用
收藏
页码:131 / 138
页数:8
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