Atomic and molecular spectra of vapors evolved in a graphite furnace. Part 5: gallium, indium and thallium nitrates and chlorides

被引:13
作者
Mofolo, RM [1 ]
Canario, CM [1 ]
Katskov, DA [1 ]
Tittarelli, P [1 ]
机构
[1] Technikon Pretoria, Dept Chem & Phys, ZA-0001 Pretoria, South Africa
关键词
atomic and molecular absorption; vaporization; graphite tube atomizer; gallium; indium; thallium;
D O I
10.1016/S0584-8547(01)00380-9
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The vaporization behavior and vapor spectra of Ga. In and Tl nitrates and chlorides in the tube furnace was investigated using an UV spectrometer with CCD detector. Fifty spectra in the wavelength range of 200-475 nm were collected in each experiment during the vaporization step, with temperature increase from 473 to 2673 K. The vaporization patterns were compared for the pyrocoated, non-pyrocoated graphite tubes, and Ta-lined tubes. Nitrate and chloride aqueous solutions and chloride slurries in chloroform were used to distinguish the impact of hydrolysis on the vaporization behavior of these chlorides. The spectra of oxygen and chlorine containing molecules, presumably of suboxides, chlorides and dichlorides were identified upon variation of the experimental conditions. The release of suboxide vapors due to the reduction of oxides by carbon was promoted after the decomposition of nitrates. The presence of other elements on the vaporization surface, or the isolation of the sample from the graphite surface by Ta-lining, impeded the vapor release and reduced the intensity of molecular bands. Adsorption of chlorine onto graphite caused a decrease of chloride and dichloride bands. The suboxide bands were observed in the spectra of Ga and In chlorides introduced in the tube as aqueous solutions, due to partial hydrolysis. (C) 2002 Elsevier Science B.V All rights reserved.
引用
收藏
页码:423 / 438
页数:16
相关论文
共 24 条
[1]   Atomic and molecular spectra of vapours evolved in a graphite furnace.: Part 2:: Magnesium chloride [J].
Daminelli, G ;
Katskov, DA ;
Mofolo, RM ;
Kántor, T .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1999, 54 (05) :683-697
[2]   Atomic and molecular spectra of vapours evolved in a graphite furnace. Part 1. Alkali halides [J].
Daminelli, G ;
Katskov, DA ;
Mofolo, RM ;
Tittarelli, P .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1999, 54 (05) :669-682
[3]  
Duval C., 1963, INORGANIC THERMOGRAV
[4]   SHADOW SPECTRAL FILMING - A METHOD OF INVESTIGATING ELECTROTHERMAL ATOMIZATION .1. DYNAMICS OF FORMATION AND STRUCTURE OF THE ABSORPTION LAYER OF THALLIUM, INDIUM, GALLIUM AND ALUMINUM ATOMS [J].
GILMUTDINOV, AK ;
ZAKHAROV, YA ;
IVANOV, VP ;
VOLOSHIN, AV .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1991, 6 (07) :505-519
[5]   SHADOW SPECTRAL FILMING - A METHOD OF INVESTIGATING ELECTROTHERMAL ATOMIZATION .2. DYNAMICS OF FORMATION AND STRUCTURE OF THE ABSORPTION LAYER OF ALUMINUM, INDIUM AND GALLIUM MOLECULES [J].
GILMUTDINOV, AK ;
ZAKHAROV, YA ;
IVANOV, VP ;
VOLOSHIN, AV ;
DITTRICH, K .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1992, 7 (04) :675-683
[6]  
Hirth J. P., 1963, CONDENSATION EVAPORA
[7]   Energy transfer caused by reactions in a graphite tube atomizer [J].
Katskov, D ;
Mofolo, R ;
Tittarelli, P .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2001, 56 (09) :1625-1644
[8]   Effect of beryllium nitrate vaporization on surface temperature in the pyrocoated graphite furnace [J].
Katskov, DA ;
Mofolo, R ;
Tittarelli, P .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1999, 54 (13) :1801-1811
[9]   Effect of magnesium nitrate vaporization on gas temperature in the graphite furnace [J].
Katskov, DA ;
Daminelli, G ;
Tittarelli, P .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1999, 54 (07) :1045-1062
[10]   APPLICATIONS OF A 2-STEP ATOMIZER AND RELATED TECHNIQUES FOR INVESTIGATING THE PROCESSES OF SAMPLE EVAPORATION AND ATOMIZATION IN ELECTROTHERMAL ATOMIC-ABSORPTION SPECTROMETRY [J].
KATSKOV, DA ;
SHTEPAN, AM ;
MCCRINDLE, RI ;
MARAIS, PJJG .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1994, 9 (03) :321-331