Activation of manganese nitrido complexes by Bronsted and Lewis acids. Crystal structure and asymmetric alkene aziridination of a chiral salen manganese nitrido complex

被引：56

作者：

Ho, CM

Lau, TC

Kwong, HL

Wong, WT

机构：

[1] City Univ Hong Kong, Dept Biol & Chem, Hong Kong, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 15期

关键词：

D O I：

10.1039/a903605i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Styrene is readily converted to 2-phenylaziridine by salen manganese(V) nitrido complexes in the presence of Bronsted or Lewis acids such as F3CCO2H or BF3, the crystal structure of a chiral manganese nitrido complex that can perform asymmetric alkene aziridination has been determined.

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页码：2411 / 2413

页数：3

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