Coordination chemistry of tris(azolyl)phosphines

被引：13

作者：

Tazelaar, Cornelis G. J. ^{[1
]}

Slootweg, J. Chris ^{[1
,2
]}

Lammertsma, Koop ^{[1
,3
]}

机构：

[1] Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, De Boelelaan 1083, NL-1081 HV Amsterdam, Netherlands

[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, Sci Pk 904,POB 94157, NL-1090 GD Amsterdam, Netherlands

[3] Univ Johannesburg, Dept Chem, Auckland Pk, ZA-2006 Johannesburg, South Africa

来源：

COORDINATION CHEMISTRY REVIEWS | 2018年 / 356卷

关键词：

Poly(azolyl) ligand; P; N ligand; Bifunctional ligand; Hemilabile ligand; Tripodal ligand; Transition metal complexes; CARBONIC-ANHYDRASE MODELS; SOLID-PHASE SYNTHESIS; PI-ALLYL COMPLEXES; MOLECULAR-STRUCTURE; ZINC-COMPLEXES; SPECTROSCOPIC PROPERTIES; COBALT(II) COMPLEXES; EFFICIENT SYNTHESIS; GOLD(I) COMPLEXES; FE(II) COMPLEXES;

D O I：

10.1016/j.ccr.2017.10.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An overview is given of the chemistry of tris(azolyl)phosphines with focus on their preparation and application in coordination- and organometallic chemistry and catalysis. These systems share with the more abundant tris(pyrazolyl)borates and -methanes the ability to function as tridentate nitrogen ligands with hemilabile character, but the additional phosphine donor site grants them bifunctional potential. Applications of tris(azolyl)phosphine complexes range from enzyme models and medicinal leads to catalysts for organic transformations and polymerization reactions, which demonstrate their versatility. (C) 2017 The Authors. Published by Elsevier B.V.

引用

收藏

页码：115 / 126

页数：12

相关论文

共 103 条

[1] NEW, IONIC SIDE-PRODUCTS IN OLIGONUCLEOTIDE SYNTHESIS - FORMATION AND REACTIVITY OF FLUORESCENT N-/PURIN-6-YL/PYRIDINIUM SALTS [J].

ADAMIAK, RW ;

BIALA, E ;

SKALSKI, B .

NUCLEIC ACIDS RESEARCH, 1985, 13 (08) :2989-3003

[2] Hydroxylation of an aliphatic C-H bond in an imidazole-ligated (mu-eta(2):eta(2)-peroxo)dicopper(II) complex [J].

Allen, WE ;

Sorrell, TN .

INORGANIC CHEMISTRY, 1997, 36 (08) :1732-1734

[3] Synthesis of oligoribonucleotides containing 4-thiouridine using the convertible nucleoside approach and the 1-(2-fluorophenyl)-4-methoxypiperidin-4-yl group [J].

Aviñó, A ;

García, RG ;

Eritja, R .

NUCLEOSIDES NUCLEOTIDES & NUCLEIC ACIDS, 2004, 23 (11) :1767-1777

[4]

BALL RG, 1984, INORG CHEM, V23, P2315, DOI 10.1021/ic00183a021

[5] Synthesis of Mg Complexes Supported by Tris-(1-pyrazolyl)phosphine [J].

Bartholomew, Amymarie K. ;

Guard, Louise M. ;

Hazari, Nilay ;

Luzik, Eddie D., Jr. .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2013, 66 (11) :1455-1458

[6] Bis[tris(1-methyl-1H-imidazol-2-yl)phosphine-κ3N3]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-κ3N3]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K) [J].

Batten, MP ;

Canty, AJ ;

Cavell, KJ ;

Rüther, T ;

Skelton, BW ;

White, AH .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 :M311-M313

[7] Mononuclear Iron-(hydro/semi)quinonate Complexes Featuring Neutral and Charged Scorpionates: Synthetic Models of Intermediates in the Hydroquinone Dioxygenase Mechanism [J].

Baum, Amanda E. ;

Lindeman, Sergey V. ;

Fiedler, Adam T. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (15-16) :2455-2464

[8] IS THE 1JPSe COUPLING CONSTANT A RELIABLE PROBE FOR THE BASICITY OF PHOSPHINES? A 31P NMR STUDY [J].

Beckmann, Udo ;

Sueslueyan, Diyana ;

Kunz, Peter C. .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2011, 186 (10) :2061-2070

[9] The synthesis, NMR and X-ray analysis of tris(1-ethyl-2-isopropylimidazol-5-yl)phosphine gold(I)-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside, a bifunctional auranofin analogue [J].

Bell, RA ;

Lock, CJL ;

Scholten, C ;

Valliant, JF .

INORGANICA CHIMICA ACTA, 1998, 274 (02) :137-142

[10] Dioxygen Reactivity of Biomimetic Fe(II) Complexes with Noninnocent Catecholate, o-Aminophenolate, and o-Phenylenediamine Ligands [J].

Bittner, Michael M. ;

Lindeman, Sergey V. ;

Popescu, Codrina V. ;

Fiedler, Adam T. .

INORGANIC CHEMISTRY, 2014, 53 (08) :4047-4061

← 1 2 3 4 5 6 7 8 9 10 →