Solid state synthesis of coordination compounds from basic metal salts

被引：87
作者：
Adams, Christopher J. [1 ]
Kurawa, Mukhtar A. [1 ]
Lusi, Matteo [1 ]
Orpen, A. Guy [1 ]
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
来源：
CRYSTENGCOMM | 2008年 / 10卷 / 12期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1039/b809950b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The preparation of the complex salts [H(2)im](2)[MCl4] (H(2)im = imidazolium, M Co, 1; Zn, 2; Cu, 3) and coordination compounds [MCl2(Him)(2)] (M = Co, 4; Zn, 5; Cu, 6) by a range of solid-state and solid-gas reactions is reported. Compounds 4-6 and the related [{MCl2(4,4'-bipy)}(n)] (M = Co, 7; Zn, 8) were prepared by the solid state reactions of metal hydroxide or carbonate salts ( or their equivalent) with the hydrochloride salt of the appropriate ligand (imidazole or 4,4'-bipy).
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收藏
页码：1790 / 1795
页数：6
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