A New Route for the Synthesis of Methylene Dibenzoate by Using An Ionic Liquid

被引：0

作者：

Likhanova, Natalya V. ^{[1
]}

Lijanova, Irina V. ^{[2
]}

Morelos Alvarado, Laura P. ^{[2
]}

Martinez Garcia, Marcos ^{[3
]}

Hernandez-Ortega, Simon ^{[3
]}

Olivares Xometl, Octavio ^{[4
]}

机构：

[1] Inst Mexicano Petr, Direcc Invest & Posgrad, Mexico City 07730, DF, Mexico

[2] Inst Politecn Nacl, CIITEC, Mexico City 02250, DF, Mexico

[3] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

[4] Benemerita Univ Autonoma Puebla, Fac Ingn Quim, Puebla 72570, Mexico

来源：

CURRENT ORGANIC CHEMISTRY | 2013年 / 17卷 / 01期

关键词：

Dichloromethane; Ionic liquids; Metilenedibenzoates; Synthesis; GREEN SOLVENTS; CARBOXYLIC-ACIDS; EFFICIENT METHOD; ESTERS; ACYLATION; DIESTERS; REAGENTS; PHENOLS; ETHERS;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ionic liquids are often used together with dichloromethane in different reactions. This combination can be problematic because the use of ionic liquids with a carboxylic acid as an anion and dichloromethane can lead to the formation of methylene diesters. The reaction of trioctylmethylammonium benzoate with dichloromethane was studied, where the ionic liquid acted as reactant, solvent and catalyst. The molecular structure of methylene dibenzoate was determined by X-ray crystallography.

引用

页码：79 / 82

页数：4

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