Iron-group electrocatalysts for ambient nitrogen reduction reaction in aqueous media

被引：163

作者：

Ma, Benyuan ^{[1
,2
]}

Zhao, Haitao ^{[1
]}

Li, Tingshuai ^{[1
]}

Liu, Qian ^{[1
]}

Luo, Yongsong ^{[1
]}

Li, Chengbo ^{[1
]}

Lu, Siyu ^{[3
,4
]}

Asiri, Abdullah M. ^{[5
,6
]}

Ma, Dongwei ^{[7
,8
]}

Sun, Xuping ^{[1
]}

机构：

[1] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Peoples R China

[2] Nanyang Normal Univ, Coll Phys & Elect Engn, Nanyang 473061, Peoples R China

[3] Zhengzhou Univ, Green Catalysis Ctr, Zhengzhou 450001, Peoples R China

[4] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China

[5] King Abdulaziz Univ, Dept Chem, Fac Sci, POB 80203, Jeddah 21589, Saudi Arabia

[6] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, POB 80203, Jeddah 21589, Saudi Arabia

[7] Henan Univ, Key Lab Special Funct Mat, Minist Educ, Kaifeng 475004, Peoples R China

[8] Henan Univ, Sch Mat Sci & Engn, Kaifeng 475004, Peoples R China

来源：

NANO RESEARCH | 2021年 / 14卷 / 03期

关键词：

nitrogen reduction reaction; electrochemical NH3 synthesis; iron-group catalysts; ambient conditions; ELECTROCHEMICAL N-2 REDUCTION; N-DOPED CARBON; EFFICIENT ELECTROCATALYST; ATMOSPHERIC-PRESSURE; N-2-TO-NH3; FIXATION; AMMONIA-SYNTHESIS; RATIONAL DESIGN; NANOSHEET ARRAY; LOW-TEMPERATURE; NH3; SYNTHESIS;

D O I：

10.1007/s12274-020-3049-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical nitrogen reduction reaction (NRR) is considered as an alternative to the industrial Haber-Bosch process for NH3 production due to both low energy consumption and environment friendliness. However, the major problem of electrochemical NRR is the unsatisfied efficiency and selectivity of electrocatalyst. As one group of the cheapest and most abundant transition metals, iron-group (Fe, Co, Ni and Cu) electrocatalysts show promising potential on cost and performance advantages as ideal substitute for traditional noble-metal catalysts. In this minireview, we summarize recent advances of iron-group-based materials (including their oxides, hydroxides, nitrides, sulfides and phosphides, etc.) as non-noble metal electrocatalysts towards ambient N-2-to-NH3 conversion in aqueous media. Strategies to boost NRR performances and perspectives for future developments are discussed to provide guidance for the field of NRR studies.

引用

页码：555 / 569

页数：15

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