Morphology characteristics and mode of CaO encapsulation during treatment of electrolytic manganese solid waste

被引：3

作者：

Du, Bing ^{[1
,2
,3
]}

Dan, Zhigang ^{[1
]}

Zhou, Changbo ^{[4
,5
]}

Guo, Tingzheng ^{[1
]}

Liu, Jianguo ^{[2
]}

Zhang, Haiyan ^{[1
]}

Shi, Feifei ^{[1
]}

Duan, Ning ^{[1
]}

机构：

[1] Chinese Res Inst Environm Sci, Technol Ctr Heavy Met Cleaner Prod Engn, Beijing, Peoples R China

[2] Tsinghua Univ, Sch Environm, Key Lab Solid Waste Management & Environm Safety, Beijing, Peoples R China

[3] Shanxi Univ, Inst Resources & Environm Engn, Taiyuan, Peoples R China

[4] Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing, Peoples R China

[5] Chinese Res Inst Environm Sci, Cleaner Prod Ctr, Beijing, Peoples R China

来源：

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH | 2016年 / 23卷 / 21期

基金：

美国国家科学基金会;

关键词：

Electrolytic manganese solid waste; Calcium oxide; Encapsulation; Secondary hydration heat; Microstructure; HEAVY-METALS; LIME; HYDRATION; MICROSTRUCTURE; IMMOBILIZATION; SOILS;

D O I：

10.1007/s11356-016-7347-0

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Electrolytic manganese solid waste (EMSW) is composed of manganese, calcium, and other sulfates. Common practice in China is to treat EMSW with quicklime (CaO); however, the per unit mass treatment efficiency of CaO is low. Studies of the interface between the CaO and EMSW particle and their microstructural characteristics are limited; these interactions may explain the low treatment efficiency. We conducted leaching experiments and measurements of the secondary heat generated by hydration of CaO to assess the extent of excess CaO in EMSW. The microstructure of CaO was also analyzed. It was determined that excess CaO particles in the EMSW were encapsulated, which influenced CaO hydration and morphology. The outer layer of the encapsulated CaO contained high levels of calcium and sulfur, which postulated to be caused by CaSO4 precipitates formed from the reaction of CaO hydration products with soluble sulfate. Three types of CaO encapsulation were identified: fully encapsulated CaO (55 % of the total CaO), partly encapsulated CaO (32 %), and self-encapsulated CaO (13 %). High concentrations of soluble sulfates in EMSW cause CaO encapsulation. These react to form CaSO4, which could negatively influence mass transfer and result in low treatment efficiency of EMSW by CaO.

引用

页码：21861 / 21871

页数：11

共 24 条

[1] Microstructure and geotechnical properties of lime-treated expansive clayey soil [J].

Al-Mukhtar, Muzahim ;

Khattab, Suhail ;

Alcover, Jean-Francois .

ENGINEERING GEOLOGY, 2012, 139 :17-27

[2] Precipitation of heavy metals from wastewater using simulated flue gas: Sequent additions of fly ash, lime and carbon dioxide [J].

Chen, Quanyuan ;

Luo, Zhou ;

Hills, Colin ;

Xue, Gang ;

Tyrer, Mark .

WATER RESEARCH, 2009, 43 (10) :2605-2614

[3] A sensitivity study for the visualisation of bacterial weathering of concrete and stone with computerised X-ray microtomography [J].

De Graef, B ;

Cnudde, V ;

Dick, J ;

De Belie, N ;

Jacobs, P ;

Verstraete, W .

SCIENCE OF THE TOTAL ENVIRONMENT, 2005, 341 (1-3) :173-183

[4]

Du B, 2015, IMMOBILIZATION MECH

[5] Immobilization of high concentrations of soluble Mn(II) from electrolytic manganese solid waste using inorganic chemicals [J].

Du, Bing ;

Hou, Deyin ;

Duan, Ning ;

Zhou, Changbo ;

Wang, Jun ;

Dan, Zhigang .

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2015, 22 (10) :7782-7793

[6] Electrolytic manganese metal industry experience based China's new model for cleaner production promotion [J].

Duan, Ning ;

Dan, Zhigang ;

Wang, Fan ;

Pan, Cenxuan ;

Zhou, Changbo ;

Jiang, Linhua .

JOURNAL OF CLEANER PRODUCTION, 2011, 19 (17-18) :2082-2087

[7] Electrokinetic Removal of Manganese from River Sediment [J].

Genc, Ayten ;

Chase, George ;

Foos, Annabelle .

WATER AIR AND SOIL POLLUTION, 2009, 197 (1-4) :131-141

[8]

Glasson D.R., 1963, Journal of Applied Chemistry, V13, P119, DOI [10.1002/jctb.5010130304, DOI 10.1002/JCTB.5010130304]

[9]

Glasson D.R., 1958, J. Appl. Chem, V8, P798

[10]

Glasson D.R., 1961, Journal of Applied Chemistry, V11, P28, DOI [https://doi.org/10.1002/jctb.5010110107, DOI 10.1002/JCTB.5010110107]

← 1 2 3 →