A novel copper-catalyzed, one-pot synthesis of symmetric organic disulfides from alkyl and aryl halides: potassium 5-methyl-1,3,4-oxadiazole-2-thiolate as a novel sulfur transfer reagent

被引:49
作者
Soleiman-Beigi, Mohammad [1 ]
Mohammadi, Fariba [1 ]
机构
[1] Ilam Univ, Dept Chem, Ilam, Iran
基金
美国国家科学基金会;
关键词
Copper-catalyzed; One-pot; Disulfides; 1,3,4-Oxadiazole; Sulfur transfer reagents; EFFICIENT SYNTHESIS; DIARYL DISULFIDES; S-S; THIOLS; OXIDATION; SULFIDES; BOND; CLEAVAGE; ALCOHOLS;
D O I
10.1016/j.tetlet.2012.10.016
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new method is reported for the synthesis of symmetric diaryl and dialkyl disulfides from aryl and alkyl halides in the presence of copper using potassium 5-methyl-1,3,4-oxadiazole-2-thiolate as the base, ligand, and sulfur-transfer reagent. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7028 / 7030
页数:3
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