Analysis of the CRDS spectrum of 18O3 between 6950 and 7125 cm-1

被引：8
作者：
Starikova, E. [2 ,3 ]
Barbe, A. [2 ]
De Backer-Barilly, M. -R. [2 ]
Tyuterev, Vl. G. [2 ]
Mondelain, D. [1 ]
Kassi, S. [1 ]
Campargue, A. [1 ]
机构：
[1] Univ Grenoble 1, CNRS, LIPhy UMR5588, F-38041 Grenoble, France
[2] UFR Sci Exactes & Nat, CNRS, UMR 7331, Grp Spectrometrie Mol & Atmospher, F-51687 Reims 2, France
[3] RAS, VE Zuev Inst Atmospher Opt SB, Lab Theoret Spect, Tomsk 634021, Russia
来源：
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 2012年 / 113卷 / 14期
关键词：
Ozone; O-18(3); Cavity Ring Down Spectroscopy; Effective Hamiltonian model; CW-CAVITY RING; OZONE MOLECULE; FOURIER-TRANSFORM; HOT-BAND; SPECTROSCOPY; O-16(3); COEFFICIENTS; REGION; STATE;
D O I：
10.1016/j.jqsrt.2012.04.023
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The absorption spectrum of the O-18(3) isotopologue of ozone was recorded by CW-Cavity Ring Down Spectroscopy in the 6950-7125 cm(-1) region. The typical noise equivalent absorption of the recordings is alpha(min) approximate to 1 x 10(-10) cm(-1). The spectrum is dominated by three very weak bands: 3 nu(1)+5 nu(3) near 7009 cm(-1) and the nu(2)+7 nu(3) and 4 nu(2)+5 nu(3) interacting bands near 7100 cm(-1). In total 260,206 and 133 transitions were assigned for the 3 nu(1)+5 nu(3), nu(2)+7 nu(3) and 4 nu(2)+5 nu(3) bands, respectively. The line positions of the 3 nu(1)+5 nu(3) band were modelled using an effective Hamiltonian (EH) model involving two dark states - (6 0 1) and (2 5 2) - in interaction with the (3 0 5) bright state. The EH model developed for the nu(2)+7 nu(3) and 4 nu(2)+5 nu(3) bands involves only the (0 1 7) and (0 4 5) interacting bright states. Line positions could be reproduced with rms deviations on the order of 0.01 cm(-1) and the dipole transition moment parameters were determined for the three observed bands. The obtained set of parameters and the experimentally determined energy levels were used to generate a list of 984 transitions of the three bands which is provided as Supplementary Material. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1741 / 1752
页数：12
相关论文
共 29 条
  • [1] CW-cavity ring down spectroscopy of the ozone molecule in the 6220-6400 cm-1 region
    Barbe, A.
    De Backer-Barilly, M. -R.
    Tyuterev, Vl. G.
    Kassi, S.
    Campargue, A.
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 2007, 246 (01) : 22 - 38
  • [2] CW-Cavity Ring Down Spectroscop, of the ozone molecule in the 5980-6220 cm-1 region
    Barbe, A.
    De Backer-Barilly, M.-R.
    Tyuterev, Vl. G.
    Campargue, A.
    Romanini, D.
    Kassi, S.
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 2007, 242 (02) : 156 - 175
  • [3] Detection and analysis of new bands of 16O3 by CRDS between 6500 and 7300 cm-1
    Barbe, A.
    De Backer-Barilly, M. -R.
    Tyuterev, Vl. G.
    Kassi, S.
    Campargue, A.
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 2011, 269 (02) : 175 - 186
  • [4] The near infrared spectrum of ozone by CW-cavity ring down spectroscopy between 5850 and 7000 cm-1:: new observations and exhaustive review
    Campargue, A.
    Barbe, A.
    De Backer-Barilly, M. -R.
    Tyuterev, Vl. G.
    Kassi, S.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (20) : 2925 - 2946
  • [5] CW-cavity ring down spectroscopy of the ozone molecule in the 6625-6830 cm-1 region
    Campargue, A.
    Kassi, S.
    Romanini, D.
    Barbe, A.
    De Backer-Barilly, M-R.
    Tyuterev, Vl. G.
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 2006, 240 (01) : 1 - 13
  • [6] CW-Cavity Ring Down spectroscopy of 18O3. Part 1: Experiment and analysis of the 6200-6400 cm-1 spectral region
    Campargue, A.
    Liu, A. W.
    Kassi, S.
    De Backer-Barilly, M. -R.
    Barbe, A.
    Starikova, E.
    Tashkun, S. A.
    Tyuterev, Vi. G.
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 2009, 255 (02) : 75 - 87
  • [7] Camy-Peyret C, 1975, THESIS U P M CURIE P
  • [8] Chichery A., 2000, PhD Thesis
  • [9] Detection and analysis of four new bands in CRDS 16O3 spectra between 7300 and 7600 cm-1
    De Backer, M. -R.
    Barbe, A.
    Starikova, E.
    Tyuterev, Vl G.
    Kassi, S.
    Campargue, A.
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 2012, 272 (01) : 43 - 50
  • [10] Fourier transform and high sensitivity cw-cavity ringdown absorption spectroscopies of ozone in the 6030-6130 cm-1 region.: First observation and analysis of the 3v1+3v3 and 2v2+5v3 bands
    De Backer-Barilly, M. -R.
    Barbe, A.
    Tyuterev, Vl. G.
    Romanini, D.
    Moeskops, B.
    Campargue, A.
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2006, 780-81 : 225 - 233
123