Electrical Properties of Ba0.96Ca0.04Ti0.90Sn0.10O3 Lead-Free Ceramics with the Addition of Nano-CeO2

被引:1
作者
Zhao, Tian-Xiang [1 ]
Qiu, Jian-Hua [1 ,3 ]
Ma, Ming-Gang [2 ]
Chen, Zhi-Hui [1 ]
Li, Cheng-Bo [2 ]
Jia, Xu-Guang [1 ]
机构
[1] Changzhou Univ, Jiangsu Prov Cultivat Base State Key Lab Photovol, Jiangsu Collaborat Innovat Ctr Photovolat Sci & E, Sch Math & Phys, Changzhou 213164, Jiangsu, Peoples R China
[2] Benxi Iron & Steel Co Ltd, Benxi 117000, Liaoning, Peoples R China
[3] Jiangsu Univ, Sch Mech Engn, Zhenjiang 212013, Jiangsu, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
BCTS Ceramics; Nano-CeO2; Electrical Properties; FERROELECTRIC PROPERTIES; PIEZOELECTRIC PROPERTIES; DIELECTRIC-PROPERTIES; BA0.9CA0.1TI0.9SN0.1O3; CERAMICS; COEFFICIENT;
D O I
10.1166/jnn.2019.16574
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Well dispersed CeO2 nanoparticles are prepared by azeotropic co-precipitation method. (Ba0.96Ca0.04)(Ti0.30Sn0.10)O-3 lead-free piezoelectric ceramics doped with nano-CeOP2(x = 0 mol%, 0.03 mol%, and 0.07 mol%) and micro-CeO2(x = 0.03 mol%) are prepared at 1430 degrees C for 2 h by the conventional solid state sintering method. XRD diffraction indicates that all components have typical perovskite structure. Both doping of nano-CeO2 and micro-CeO2 can inhibit grain growth. And the average grain size decreased apparently with the increase of nano-CeO2 amount. All the samples exhibit typical diffuse phase transition behavior. The optimized electrical performances are obtained at x = 0.03 mol% with d(33) = 512 pC/N, k(p) = 41.5%, and P-r = 14.00 mu C/cm(2).
引用
收藏
页码:5661 / 5666
页数:6
相关论文
共 30 条
[1]   STUDY OF DIELECTRIC-PROPERTIES OF NANO-PARTICLES OF CADMIUM-SULFIDE [J].
ABDULKHADAR, M ;
THOMAS, B .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1995, 150 (02) :755-762
[2]   Grain size and domain size relations in bulk ceramic ferroelectric materials [J].
Cao, WW ;
Randall, CA .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (10) :1499-1505
[3]   Synthesis of highly sinterable YAG nanopowders by a modified co-precipitation method [J].
Chen, Zhi-Hui ;
Yang, Yun ;
Hu, Zhang-Gui ;
Li, Jiang-Tao ;
He, Shu-Li .
JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 433 (1-2) :328-331
[4]   Enhanced piezoelectric properties in (Ba1-xCax)(Ti0.90Sn0.10)O3-0.08Dy2O3 lead-free ceramics [J].
Chen, Zhi-hui ;
Li, Zhi-wei ;
Ma, Ming-gang ;
Qiu, Jian-hua ;
Zhao, Tian-xiang ;
Ding, Jian-ning ;
Jia, Xu-guang ;
Zhu, Ke-qian .
MATERIALS RESEARCH BULLETIN, 2018, 105 :330-333
[5]   Y2O3 doped Ba0.9Ca0.1Ti0.9Sn0.1O3 ceramics with improved piezoelectric properties [J].
Chen, Zhi-hui ;
Li, Zhi-wei ;
Qiu, Jian-hua ;
Zhao, Tian-xiang ;
Ding, Jian-ning ;
Jia, Xu-guang ;
Zhu, Wei-qin ;
Xu, Jiu-jun .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2018, 38 (04) :1349-1355
[6]   Improvement on electrical properties of Ba0.9Ca0.1Ti0.9Sn0.1O3 ceramics with the addition of CeO2 [J].
Chen, Zhi-hui ;
Li, Zhi-wei ;
Xu, Jiu-jun ;
Guo, Hua-fei ;
Zhang, Bing ;
Ding, Jian-ning ;
Qiu, Jian-hua .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 720 :562-566
[7]   Piezoelectric and ferroelectric properties of Ba0.9Ca0.1Ti0.9Sn0.1O3 lead-free ceramics with La2O3 addition [J].
Chen, Zhi-hui ;
Li, Zhi-wei ;
Ding, Jian-ning ;
Qiu, Jian-hua ;
Yang, Ya .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 704 :193-196
[8]   Dy2O3 Doped (Ba0.85Ca0.15)(Ti0.90Zr0.10)O3 Ceramics [J].
Chen Zhi-Hui ;
Ding Jian-Ning ;
Xu Jiu-Jun ;
Shan Ying-Chun ;
Qu Jie ;
Qiu Jian-Hua .
FERROELECTRICS, 2014, 460 (01) :49-56
[9]   Effect of Nd2O3 doping on the electrical properties of Ba0.96Ca0.04Ti0.90Sn0.10O3 ceramics [J].
Chen, Zhihui ;
Li, Zhiwei ;
Ma, Minggang ;
Zhao, Tianxiang ;
Qiu, Jianhua ;
Ding, Jianning .
JOURNAL OF RARE EARTHS, 2018, 36 (07) :745-749
[10]   Lead-free (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3-CeO2 ceramics with high piezoelectric coefficient obtained by low-temperature sintering [J].
Cui, Yerang ;
Liu, Xinyu ;
Jiang, Minhong ;
Zhao, Xiayan ;
Shan, Xu ;
Li, Wenhua ;
Yuan, Changlai ;
Zhou, Changrong .
CERAMICS INTERNATIONAL, 2012, 38 (06) :4761-4764