One-Pot Click Access to a Cyclodextrin Dimer-Based Novel Aggregation Induced Emission Sensor and Monomer-Based Chiral Stationary Phase

被引：5
作者：
Li, Xiaoli [1 ,2 ]
Zhao, Rui [1 ,2 ]
Tang, Xiaoying [1 ,2 ]
Shi, Yanyan [1 ,2 ]
Li, Chunyi [2 ]
Wang, Yong [1 ,2 ]
机构：
[1] Tianjin Univ, Sch Sci, Dept Chem, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300072, Peoples R China
[2] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
来源：
SENSORS | 2016年 / 16卷 / 12期
基金：
中国国家自然科学基金;
关键词：
click; cyclodextrin; aggregation induced emission; chiral stationary phase; BETA-CYCLODEXTRIN; FLUORESCENT CHEMOSENSOR; PROBE; TETRAPHENYLETHYLENE; STEREOISOMERS; SEPARATION; CONJUGATE; CHEMISTRY;
D O I：
10.3390/s16121985
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A 'two birds, one stone' strategy was developed via a one-pot click reaction to simultaneously prepare a novel cyclodextrin (CD) dimer based aggregation induced emission (AIE) sensor (AIE-DCD) and a monomer based chiral stationary phase (CSP-MCD) for chiral high performance liquid chromatography (CHPLC). AIE-DCD was found to afford satisfactory AIE response for specific detection of Zn2+ with a detection limit of 50 nM. CSP-MCD exhibits excellent enantioseparation ability toward dansyl amino acids, where the resolution of dansyl amino leucine reaches 5.43.
引用
收藏
页码：2 / 9
页数：9
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