First synthesis and aggregation behaviour of periconjugated triazoliumfullerene

被引：12
|
作者：
Ikuma, Naohiko [1 ]
Inaba, Saori [1 ]
Kokubo, Ken [1 ]
Oshima, Takumi [1 ]
机构：
[1] Osaka Univ, Div Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 05期
关键词：
1,3-DIAZA-2-AZONIAALLENE SALTS; CYCLOADDITION REACTIONS; WATER; FULLERENES;
D O I：
10.1039/c3cc45783d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Triazoliumfullerene was first prepared by the [3+2] cycloaddition of in situ generated 1,3-diaza-2-azoniaallene with fullerene and was characterized by the dispersed positive charge over the fullerene sphere associated with periconjugation. This new type of amphiphilic fullerene tended to form vesicles and crystalline aggregates after the casting of THF or MeOH solutions.
引用
收藏
页码：581 / 583
页数：3
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