Pyrrole synthesis in ionic liquids by Paal-Knorr condensation under mild conditions

被引：108

作者：

Wang, B ^{[1
]}

Gu, YL ^{[1
]}

Luo, C ^{[1
]}

Yang, T ^{[1
]}

Yang, LM ^{[1
]}

Suo, JS ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 17期

关键词：

Paal-Knorr; ionic liquid; 2.5-1-hexandione; primary amine; pyrrole;

D O I：

10.1016/j.tetlet.2004.03.012

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Paal-Knorr condensation of 15-hexandione with primary amines was successfully carried out in ionic liquids. Through investigating different ionic liquids, different reaction times. the reaction. using ionic liquids its solvent, exhibited simple product isolation procedure, improved yields and exclusive selectivity and the mild conditions and the avoidance of using toxic Catalysts are also its special features. Recovery and reuse of ionic liquid are also satisfactory. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：3417 / 3419

页数：3

共 22 条

[1]

Ballini R, 2000, SYNLETT, P391

[2]

Chowdari NS, 2003, SYNLETT, P1906

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