The synthesis, characterization of three isomers of rhodamine derivative and their application in copper (II) ion recognition

被引：43

作者：

Huo, Fangjun ^{[1
]}

Wang, Long ^{[1
]}

Yin, Caixia ^{[2
]}

Yang, Yutao ^{[2
]}

Tong, Hongbo ^{[1
]}

Chao, Jianbin ^{[1
]}

Zhang, Yongbin ^{[1
]}

机构：

[1] Shanxi Univ, Res Inst Appl Chem, Taiyuan 030006, Peoples R China

[2] Shanxi Univ, Inst Mol Sci, Minist Educ, Key Lab Chem Biol & Mol Engn, Taiyuan 030006, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2013年 / 188卷

基金：

中国国家自然科学基金; 山西省青年科学基金;

关键词：

Rhodamine derivative; UV-Vis spectra; Copper ion; Fluorescence spectra; Bioimaging; VISUAL DETECTION; METAL IONS; FLUORESCENT; CHEMOSENSOR; CU2+; GOLD; NANOPARTICLES; CHEMISTRY; CU(II); SENSOR;

D O I：

10.1016/j.snb.2013.07.102

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Three isomers of rhodamine derivative, ortho-pyridylaldehyde rhodamine hydrazone (1), meta-pyridylaldehyde rhodamine hydrazone (2), and para-pyridylaldehyde rhodamine hydrazone (3) were synthesized and characterized. And their recognition abilities for Cu2+ were studied by UV-Vis spectra. The result showed that ortho-pyridylaldehyde rhodamine hydrazone (1) due to having a suitable space coordination structure is a best selective probe for Cu2+ over other metal ions in 10 mmol/L HEPES buffer, pH 7.0/CH3OH (v/v, 1:1), and that it is a quick colorimetric and lagged fluorometric dual-model probe for Cu2+. Because it is a fluorescence turn-on probe, cell experiments show probe can permeate through cell membranes and react to Cu2+ within living cells. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：735 / 740

页数：6

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