Li-B Alloy as Anode Material for Lithium/Sulfur Battery

被引:65
作者
Duan, Bochao [1 ,2 ]
Wang, Weikun [2 ]
Zhao, Hailei [1 ]
Wang, Anbang [2 ]
Wang, Mengjia [3 ]
Yuan, Keguo [2 ]
Yu, Zhongbao [2 ]
Yang, Yusheng [1 ,2 ]
机构
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[2] Res Inst Chem Def, Beijing 100191, Peoples R China
[3] Beijing Univ Chem Technol, Sch Mat Sci & Engn, Beijing 100029, Peoples R China
关键词
SULFUR BATTERIES; COMPOUND; ELECTROLYTE; COMPOSITE;
D O I
10.1149/2.005306eel
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electrochemical performance of Li-B alloy as anode for lithium/sulfur battery is firstly investigated. Compared with the common metal Li anode, Li-B alloy has better behaviors in restraining the formation of dendritic lithium, reducing the interface impedance of electrode and improving the cycle performance of the battery due to its unique structure which contains free metal lithium filled in the fibrillar network framework of Li/B compound. Test results show that the Li-B alloy has great potential as a promising anode material for lithium/sulfur battery. (C) 2013 The Electrochemical Society. [DOI: 10.1149/2.005306eel] All rights reserved.
引用
收藏
页码:A47 / A51
页数:5
相关论文
共 16 条
[1]   A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions [J].
Aurbach, D ;
Zinigrad, E ;
Cohen, Y ;
Teller, H .
SOLID STATE IONICS, 2002, 148 (3-4) :405-416
[2]   The application of atomic force microscopy for the study of Li deposition processes [J].
Aurbach, D ;
Cohen, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (11) :3525-3532
[3]   Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries [J].
Jayaprakash, N. ;
Shen, J. ;
Moganty, Surya S. ;
Corona, A. ;
Archer, Lynden A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (26) :5904-5908
[4]   Advances in Li-S batteries [J].
Ji, Xiulei ;
Nazar, Linda F. .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (44) :9821-9826
[5]   Electrochemical performance of lithium/sulfur batteries with protected Li anodes [J].
Lee, YM ;
Choi, NS ;
Park, JH ;
Park, JK .
JOURNAL OF POWER SOURCES, 2003, 119 :964-972
[6]   A Polyaniline-Coated Sulfur/Carbon Composite with an Enhanced High-Rate Capability as a Cathode Material for Lithium/Sulfur Batteries [J].
Li, Guo-Chun ;
Li, Guo-Ran ;
Ye, Shi-Hai ;
Gao, Xue-Ping .
ADVANCED ENERGY MATERIALS, 2012, 2 (10) :1238-1245
[7]   Improved cycling performances of lithium sulfur batteries with LiNO3-modified electrolyte [J].
Liang, Xiao ;
Wen, Zhaoyin ;
Liu, Yu ;
Wu, Meifen ;
Jin, Jun ;
Zhang, Hao ;
Wu, Xiangwei .
JOURNAL OF POWER SOURCES, 2011, 196 (22) :9839-9843
[8]   Electrochemical behavior and morphology of LiB compound anode materials [J].
Liu, ZJ ;
Yin, J ;
Meng, ZQ ;
Chong, J ;
Zhou, DB .
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2006, 16 (01) :127-131
[9]   Effect of carbon dioxide on lithium anode cycleability with various substrates [J].
Osaka, T ;
Momma, T ;
Matsumoto, Y ;
Uchida, Y .
JOURNAL OF POWER SOURCES, 1997, 68 (02) :497-500
[10]  
SANCHEZ P, 1992, J MATER SCI, V27, P240, DOI 10.1007/BF02403669