Surface energy and polarity of treated indium-tin-oxide anodes for polymer light-emitting diodes studied by contact-angle measurements

被引:160
作者
Kim, JS [1 ]
Friend, RH [1 ]
Cacialli, F [1 ]
机构
[1] Univ Cambridge, Cavendish Lab, Optoelect Grp, Cambridge CB3 0HE, England
关键词
D O I
10.1063/1.371124
中图分类号
O59 [应用物理学];
学科分类号
摘要
We present contact-angle hysteresis and surface energy of differently treated indium-tin-oxide (ITO) thin films obtained from contact angles for liquids with different polar character. We find that the hysteresis and the polar and dispersion component of the surface energy depend strongly on the surface treatments. Oxygen-plasma treatments induce the highest polarity and the highest total surface energy, and we suggest that this improves the interface formation with polymers, and therefore, the performance of light-emitting diodes. We discuss the results in relation to the ITO surface roughness and chemical heterogeneity modified by the different treatments. (C) 1999 American Institute of Physics. [S0021-8979(99)04417-5].
引用
收藏
页码:2774 / 2778
页数:5
相关论文
共 18 条
[1]   EFFECT OF ADSORBED WATER ON WETTING PROPERTIES OF BOROSILICATE GLASS QUARTZ AND SAPPHIRE [J].
BERNETT, MK ;
ZISMAN, WA .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1969, 29 (03) :413-&
[2]   Viscoelastic effects in the spreading of liquids [J].
Carre, A ;
Gastel, JC ;
Shanahan, MER .
NATURE, 1996, 379 (6564) :432-434
[3]   Using vibrational noise to probe energy barriers producing contact angle hysteresis [J].
Decker, EL ;
Garoff, S .
LANGMUIR, 1996, 12 (08) :2100-2110
[4]   An experimental study of contact angle hysteresis [J].
Extrand, CW ;
Kumagai, Y .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 191 (02) :378-383
[5]   LIQUID-DROPS ON AN INCLINED PLANE - THE RELATION BETWEEN CONTACT ANGLES, DROP SHAPE, AND RETENTIVE FORCE [J].
EXTRAND, CW ;
KUMAGAI, Y .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1995, 170 (02) :515-521
[6]   Contact angles and hysteresis on soft surfaces [J].
Extrand, CW ;
Kumagai, Y .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 184 (01) :191-200
[7]   Improved operational stability of polyfluorene-based organic light-emitting diodes with plasma-treated indium-tin-oxide anodes [J].
Kim, JS ;
Friend, RH ;
Cacialli, F .
APPLIED PHYSICS LETTERS, 1999, 74 (21) :3084-3086
[8]   Increase of charge carriers density and reduction of Hall mobilities in oxygen-plasma treated indium-tin-oxide anodes [J].
Kim, JS ;
Cacialli, F ;
Cola, A ;
Gigli, G ;
Cingolani, R .
APPLIED PHYSICS LETTERS, 1999, 75 (01) :19-21
[9]   Indium-tin oxide treatments for single- and double-layer polymeric light-emitting diodes: The relation between the anode physical, chemical, and morphological properties and the device performance [J].
Kim, JS ;
Granstrom, M ;
Friend, RH ;
Johansson, N ;
Salaneck, WR ;
Daik, R ;
Feast, WJ ;
Cacialli, F .
JOURNAL OF APPLIED PHYSICS, 1998, 84 (12) :6859-6870
[10]   CONTACT-ANGLE HYSTERESIS ON HETEROGENEOUS SMOOTH SURFACES [J].
MARMUR, A .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1994, 168 (01) :40-46