Recent Advances and Emerging Trends in Photo-Electrochemical Solar Energy Conversion

被引：259

作者：

Tilley, S. David ^{[1
]}

机构：

[1] Univ Zurich, Dept Chem, Winterthurerstr 190, CH-8057 Zurich, Switzerland

来源：

ADVANCED ENERGY MATERIALS | 2019年 / 9卷 / 02期

基金：

瑞士国家科学基金会;

关键词：

hydrogen; photo-electrochemical; value-added chemicals; water splitting; HYDROGEN-PRODUCTION; THIN-FILM; OXYGEN EVOLUTION; H-2; EVOLUTION; CU2ZNSNS4; PHOTOCATHODES; HEMATITE PHOTOANODES; BIVO4; PHOTOANODES; CHARGE COLLECTION; WATER; EFFICIENT;

D O I：

10.1002/aenm.201802877

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photo-electrochemical (PEC) solar energy conversion offers the promise of low-cost renewable fuel generation from abundant sunlight and water. In this Review, recent developments in photo-electrochemical water splitting are discussed with respect to this promise. State-of-the-art photo-electrochemical device performance is put in context with the current understanding of the necessary requirements for cost-effective solar hydrogen generation (in terms of solar-to-hydrogen conversion efficiency and system durability, in particular). Several important studies of photo-electrochemical hydrogen generation at p-type photocathodes are highlighted, mostly with protection layers (for enhanced durability), but also a few recent examples where protective layers are not needed. Recent work with the widely studied n-type BiVO4 photoanode is detailed, which highlights the needs and necessities for the next big photoanode material yet to be discovered. The emerging new research direction of photo-electrocatalytic upgrading of biomass substrates toward value-added chemicals is then discussed, before closing with a commentary on how research on PEC materials remains a worthwhile endeavor.

引用

页数：13

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