Synthesis and reactivity of 6-mercapto-6H-dibenzo[c,e][1,2]oxaphosphinine 6-sulfide

被引：0
作者：
Rakotomalala, Muriel [1 ]
Ciesielski, Michael [1 ]
Walter, Olaf [2 ]
Doering, Manfred [1 ]
机构：
[1] Karlsruhe Inst Technol, Inst Catalysis Res & Technol, D-76344 Eggenstein Leopoldshafen, Germany
[2] European Commiss Joint Res Ctr, Inst Transuranium Elements, D-76344 Eggenstein Leopoldshafen, Germany
来源：
ARKIVOC | 2012年
关键词：
6H-Dibenzo[c,e][1,2]oxaphosphinine; sulfur; phosphorus; rearrangement; thiol-Michael reaction; EPOXY-RESINS; FLAME-RETARDANTS; PHOSPHORUS; CHEMISTRY; POLYMERS; DOPO;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis route of the novel 6-mercapto-6H-dibenzo[c,e][1,2]oxaphosphinine 6-sulfide 4 from 6-chloro-6H-dibenzo[c,e][1,2]oxaphosphinine 1 and its spectroscopic investigation are presented. In addition, reaction of the thiol group with unsaturated functionalities such as acrylates demonstrated that the newly synthesized compound could undergo thiol-ene chemistry. Moreover, modification of the reaction condition led to the formation of the rearrangement product of a thiol-Michael reaction of compound 4 with benzoquinone.
引用
收藏
页码：470 / 483
页数：14
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