Efficient transfer hydrogenation of carbonyl compounds catalyzed by selenophenolato hydrido iron(II) complexes

被引：9
作者：
Wang, Yangyang [1 ,2 ]
Du, Zhengyin [1 ]
Zheng, Tingting [2 ,3 ]
Sun, Hongjian [2 ]
Li, Xiaoyan [2 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China
[2] Shandong Univ, Minist Educ, Key Lab Special Funct Aggregated Mat, Sch Chem & Chem Engn, Shanda Nanlu 27, Jinan 250100, Shandong, Peoples R China
[3] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2019年 / 124卷
关键词：
TH; Iron hydride; Ketone; Aldehyde; Isopropanol; ASYMMETRIC TRANSFER HYDROGENATION; KETONES; REDUCTION;
D O I：
10.1016/j.catcom.2019.02.027
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Selenophenolato hydrido iron(II) complexes 1-3 cis-[(H)(SeAr)Fe(PMe3)(4)] (Ar = C6H5 (1), p-MeOC6H4 (2) and o-MeC6H4 (3)) could catalyze transfer hydrogenation of aldehydes and ketones. Among the three complexes, catalyst 1 exhibited the highest catalytic activity. The catalytic reactions took place under very mild conditions, using isopropanol as solvent and hydrogen source, (BuONa)-Bu-t as base under 60-80 degrees C. This catalytic system has good tolerance for many functional groups, such as halides, C=C double bonds, nitro groups and cyano groups at the phenyl ring of the substrates.
引用
收藏
页码：32 / 35
页数：4
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