Spatial Distribution, Source Identification, and Potential Ecological Risk Assessment of Heavy Metal in Surface Sediments from River-Reservoir System in the Feiyun River Basin, China

To investigate the pollution characteristics of the surface sediments of the river-reservoir system in the Feiyun River basin, a sediment heavy metal survey was conducted for the first time in the Feiyun River basin. Surface sediments from 21 sampling sites in the Feiyun River basin were collected, and the concentrations and spatial distribution characteristics of 15 heavy metals (Cr, Ni, Cu, Zn, As, Cd, Pb, Mn, V, Co, Mo, Sb, W, Fe, and Se) were analyzed. Three heavy metal ecological risk assessment methods were used to evaluate the potential risks of heavy metals in sediments, and the sources of major heavy metals were traced by correlation analysis and principal component analysis. The results show that (1) the average concentration of heavy metals (As) (212.64 mg/kg) and (Sb) (4.89 mg/kg) in Feiyun River Basin is 33.3 and 6.89 times the background value of Zhejiang Province; the overall spatial distribution of heavy metals is: the mainstream of Feiyun River > Zhaoshandu Reservoir > Shanxi Reservoir, thereby, the pollution is relatively significant; (2) by processing the geo-accumulation index and enrichment index methods, As and Sb are classified as 'severely polluted', 'moderately severely polluted' and 'severely polluted', 'very severe polluted' respectively; (3) the potential ecological index evaluates the surface sediments in the Feiyun River Basin as a very high risk level, the main environmental risk factors are As, Sb, Cd and Mo; (4) the principal component analysis results show that the heavy metals in the sediments of the Feiyun River Basin may be mainly affected by human activities such as sewage from domestic and agricultural activities, mining and smelting, and the others are affected by natural factors.