Specific recognition of fluoride anion using a metallamacrocycle incorporating a uranyl-salen unit

被引：39

作者：

Cametti, Massimo ^{[1
,2
,3
]}

Cort, Antonella Dalla ^{[1
,2
]}

Mandolini, Luigi ^{[1
,2
]}

Nissinen, Maija ^{[3
]}

Rissanen, Kari ^{[3
]}

机构：

[1] Univ Roma La Sapienza, IMC CNR, I-00185 Rome, Italy

[2] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

[3] Univ Jyvaskyla, Dept Chem, Nanosci Ctr, FIN-40014 Jyu, Finland

来源：

NEW JOURNAL OF CHEMISTRY | 2008年 / 32卷 / 07期

关键词：

D O I：

10.1039/b806149a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design and synthesis of a novel fluoride receptor that uses a salen-complexed Lewis acidic uranyl center as the sole binding site is reported here. This receptor binds fluoride anions in DMSO with a high affinity constant (K > 10(6) M(-1)) and exhibits a negligible affinity (K < 10 M(-1)) towards otherwise effective competitors, such as acetate, phosphate and cyanide anions.

引用

页码：1113 / 1116

页数：4

共 32 条

[1] What anions do to N-H-containing receptors [J].

Amendola, Valeria ;

Esteban-Gomez, David ;

Fabbrizzi, Luigi ;

Licchelli, Maurizio .

ACCOUNTS OF CHEMICAL RESEARCH, 2006, 39 (05) :343-353

[2] Some guidelines for the design of anion receptors [J].

Amendola, Valeria ;

Bonizzoni, Marco ;

Esteban-Gomez, David ;

Fabbrizzi, Luigi ;

Licchelli, Maurizio ;

Sancenon, Felix ;

Taglietti, Angelo .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (11-12) :1451-1470

[3] Neutral anion receptors: design and application [J].

Antonisse, MMG ;

Reinhoudt, DN .

CHEMICAL COMMUNICATIONS, 1998, (04) :443-448

[4] Highly selective optical fluoride ion sensor with submicromolar detection limit based on aluminum(III) octaethylporphyrin in thin polymeric film [J].

Badr, IHA ;

Meyerhoff, ME .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (15) :5318-5319

[5] Isophthalamides and 2,6-dicarboxamidopyridines with pendant indole groups: a 'twisted' binding mode for selective fluoride recognition [J].

Bates, Gareth W. ;

Gale, Philip A. ;

Light, Mark E. .

CHEMICAL COMMUNICATIONS, 2007, (21) :2121-2123

[6] Amide based receptors for anions [J].

Bondy, CR ;

Loeb, SJ .

COORDINATION CHEMISTRY REVIEWS, 2003, 240 (1-2) :77-99

[7] Recognition of alkali metal halide contact ion pairs by uranyl-salophen receptors bearing aromatic sidearms.: The role of cation-π interactions [J].

Cametti, M ;

Nissinen, M ;

Cort, AD ;

Mandolini, L ;

Rissanen, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (11) :3831-3837

[8] Ion pair recognition of quaternary ammonium and iminium salts by uranyl-salophen compounds in solution and in the solid state [J].

Cametti, Massimo ;

Nissinen, Maija ;

Cort, Antonella Dalla ;

Mandolini, Luigi ;

Rissanen, Kari .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (12) :3641-3648

[9] Crystal structure of a CsF-Uranyl-Salen complex. An unusual cesium-chlorine coordination [J].

Cametti, Massimo ;

Nissinen, Maija ;

Dalla Cort, Antonella ;

Rissanen, Kari ;

Mandolini, Luigi .

INORGANIC CHEMISTRY, 2006, 45 (16) :6099-6101

[10] Molecular recognition of carbonyl compounds by uranyl-salophen based neutral receptors driven by Van der Waals forces [J].

Castelli, VV ;

Dalla Cort, A ;

Mandolini, L ;

Pinto, V ;

Reinhoudt, DN ;

Ribaudo, F ;

Sanna, C ;

Schiaffino, L ;

Snellink-Ruël, BHM .

SUPRAMOLECULAR CHEMISTRY, 2002, 14 (2-3) :211-219

← 1 2 3 4 →