Deactivation of sulfonated hydrothermal carbons in the presence of alcohols: Evidences for sulfonic esters formation

被引：95
作者：
Fraile, Jose M. [1 ]
Garcia-Bordeje, Enrique [2 ]
Roldan, Laura [1 ]
机构：
[1] Univ Zaragoza, ISQCH, Fac Ciencias, CSIC, E-50009 Zaragoza, Spain
[2] Inst Carboquim ICB CSIC, E-50018 Zaragoza, Spain
来源：
JOURNAL OF CATALYSIS | 2012年 / 289卷
关键词：
Sulfonated hydrothermal carbons; Esterification; Deactivation; Acid catalysts; SOLID ACID CATALYST; BIODIESEL PRODUCTION; AMORPHOUS-CARBON; ESTERIFICATION; METHANOL; GLUCOSE; SPHERES; CARBONIZATION; TRANSESTERIFICATION; NANOSPHERES;
D O I：
10.1016/j.jcat.2012.01.017
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Sulfonated hydrothermal carbons present high activity for esterification of palmitic acid with alcohols. However, the catalyst is significantly deactivated upon recovery. Leaching of sulfonated species does not account for this deactivation, which is observed even by pretreatment only with the alcohol under reflux. Solid state NMR shows the presence of chemically bound alkyl groups coming from the alcohol, clearly different from strongly physisorbed species obtained by pretreatment at room temperature. The formation of sulfonate esters accounts for the deactivation behavior in reactions taking place in alcohols as solvents, mainly with methanol due to its higher reactivity. (C) 2012 Elsevier Inc. All rights reserved.
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页码：73 / 79
页数：7
相关论文
共 40 条
[1]   Deactivation of organosulfonic acid functionalized silica catalysts during biodiesel synthesis [J].
Alba-Rubio, A. C. ;
Vila, F. ;
Martin Alonso, D. ;
Ojeda, M. ;
Mariscal, R. ;
Lopez Granados, M. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 95 (3-4) :279-287
[2]  
Anastas P., 1998, GREEN CHEM THEORY PR
[3]   Structural Characterization of Hydrothermal Carbon Spheres by Advanced Solid-State MAS 13C NMR Investigations [J].
Baccile, Niki ;
Laurent, Guillaume ;
Babonneau, Florence ;
Fayon, Franck ;
Titirici, Maria-Magdalena ;
Antonietti, Markus .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (22) :9644-9654
[4]   Versatile mesoporous carbonaceous materials for acid catalysis [J].
Budarin, Vitaly L. ;
Clark, James H. ;
Luque, Rafael ;
Macquarrie, Duncan J. .
CHEMICAL COMMUNICATIONS, 2007, (06) :634-636
[5]   Solid acids for green chemistry [J].
Clark, JH .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :791-797
[6]   Heterogeneous catalysts for biodiesel production [J].
Di Serio, Martino ;
Tesser, Riccardo ;
Pengmei, Lu ;
Santacesaria, Elio .
ENERGY & FUELS, 2008, 22 (01) :207-217
[7]   A Low-Concentration Hydrothermal Synthesis of Biocompatible Ordered Mesoporous Carbon Nanospheres with Tunable and Uniform Size [J].
Fang, Yin ;
Gu, Dong ;
Zou, Ying ;
Wu, Zhangxiong ;
Li, Fuyou ;
Che, Renchao ;
Deng, Yonghui ;
Tu, Bo ;
Zhao, Dongyuan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (43) :7987-7991
[8]   Structure and Catalysis of Cellulose-Derived Amorphous Carbon Bearing SO3H Groups [J].
Fukuhara, Kiichi ;
Nakajima, Kiyotaka ;
Kitano, Masaaki ;
Kato, Hideki ;
Hayashi, Shigenobu ;
Hara, Michikazu .
CHEMSUSCHEM, 2011, 4 (06) :778-784
[9]   A carbon material as a strong protonic acid [J].
Hara, M ;
Yoshida, T ;
Takagaki, A ;
Takata, T ;
Kondo, JN ;
Hayashi, S ;
Domen, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2955-2958
[10]   Engineering Carbon Materials from the Hydrothermal Carbonization Process of Biomass [J].
Hu, Bo ;
Wang, Kan ;
Wu, Liheng ;
Yu, Shu-Hong ;
Antonietti, Markus ;
Titirici, Maria-Magdalena .
ADVANCED MATERIALS, 2010, 22 (07) :813-828
1234