Iron fluorophosphates

被引：30
作者：
Keates, Adam C. [1 ]
Armstrong, Jennifer A. [1 ]
Weller, Mark T. [2 ]
机构：
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 30期
关键词：
CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; PHOSPHATES; FRAMEWORKS; BATTERIES; BEHAVIOR; PHASE; ACID; FE;
D O I：
10.1039/c3dt50324k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
18 new iron fluorophosphates and a chlorofluorophosphate have been synthesised hydrothermally in a fluoride-rich medium, using FeF2, FeF3, Fe, HPF6. HCl, monovalent metal fluorides as reactants and amines as templating agents. Products have been fully structurally characterised using single crystal X-ray diffraction, and the stability of some compounds investigated using thermogravimetric analysis. Reaction in fluoride-rich conditions produce ribbon-like, layer and framework structures containing new and unusual structural motifs based on the linking of Fe(O,F)(6), PO3F, and PO2(OH,F)(2) polyhedra. Structures exhibiting inter-layer spaces and channels are frequently lined by terminal fluoride anions of the PO3F, PO2(OH,F)(2) and Fe(O,F)(6) polyhedra.
引用
收藏
页码：10715 / 10724
页数：10
相关论文
共 28 条
  • [1] Manganese(III) fluorophosphate frameworks
    Armstrong, Jennifer A.
    Williams, Edward R.
    Weller, Mark T.
    [J]. DALTON TRANSACTIONS, 2013, 42 (06) : 2302 - 2308
  • [2] Cobalt(II) fluorophosphate frameworks
    Armstrong, Jennifer A.
    Williams, Edward R.
    Weller, Mark T.
    [J]. DALTON TRANSACTIONS, 2012, 41 (46) : 14180 - 14187
  • [3] Fluoride-Rich, Hydrofluorothermal Routes to Functional Transition Metal (Mn, Fe, Co, Cu) Fluorophosphates
    Armstrong, Jennifer A.
    Williams, Edward R.
    Weller, Mark T.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (21) : 8252 - 8263
  • [4] STRUCTURE OF NI(H2O)6(NH4)2(PO3F)2
    BERRAHO, M
    RKHA, C
    VEGAS, A
    RAFIQ, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1350 - 1352
  • [5] A COPPER MONOFLUOROPHOSPHATE, CU(H2O)2(NH4)2(PO3F)2
    BERRAHO, M
    VEGAS, A
    MARTINEZRIPOLL, M
    RAFIQ, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 666 - 668
  • [6] Hydrothermal synthesis, crystal structure, thermal behavior and spectroscopic and magnetic properties of two new organically templated fluoro-vanadyl-hydrogenarsenates:: (R)0.5[(VO)(HAsO4)F] (R:: Ethylenediammonium and piperazinium)
    Berrocal, Teresa
    Mesa, Jose L.
    Pizarro, Jose L.
    Lezama, Luis
    Bazan, Begona
    Arriortua, Maria I.
    Rojo, Teofilo
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (04) : 884 - 894
  • [7] Study of a new iron phosphate catalyst for oxidative dehydrogenation of isobutyric acid
    Bonnet, P
    Millet, JMM
    Leclercq, C
    Vedrine, JC
    [J]. JOURNAL OF CATALYSIS, 1996, 158 (01) : 128 - 141
  • [8] Buxbaum G., 2005, IND INORGANIC PIGMEN, V3rd
  • [9] The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates
    Doran, MB
    Cockbain, BE
    Norquist, AJ
    O'Hare, D
    [J]. DALTON TRANSACTIONS, 2004, (22) : 3810 - 3814
  • [10] A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries
    Ellis, B. L.
    Makahnouk, W. R. M.
    Makimura, Y.
    Toghill, K.
    Nazar, L. F.
    [J]. NATURE MATERIALS, 2007, 6 (10) : 749 - 753
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