Microparticles confined to a nematic liquid crystal shell

被引:45
作者
Gharbi, Mohamed Amine [1 ,2 ]
Sec, David [3 ]
Lopez-Leon, Teresa [1 ,2 ]
Nobili, Maurizio [1 ,2 ]
Ravnik, Miha [3 ,5 ]
Zumer, Slobodan [3 ,4 ,5 ]
Blanc, Christophe [1 ,2 ]
机构
[1] Univ Montpellier 2, Lab Charles Coulomb, UMR5221, F-34095 Montpellier, France
[2] CNRS, Lab Charles Coulomb, UMR5221, F-34095 Montpellier, France
[3] Univ Ljubljana, Dept Phys, Ljubljana 1000, Slovenia
[4] Jozef Stefan Inst, Ljubljana 1000, Slovenia
[5] Ctr Excellence NAMASTE, Ljubljana 1000, Slovenia
关键词
TOPOLOGICAL DEFECTS; COLLOIDAL CRYSTALS; PHOTONIC CRYSTALS; SURFACE; ORDER; DNA; CRYSTALLIZATION; NANOPARTICLES; MICROSPHERES; PARTICLES;
D O I
10.1039/c3sm00126a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A seminal paper [D.R. Nelson, Nano Lett., 2002, 2, 1125.] has proposed that a nematic coating could be used to create a valency for spherical colloidal particles through the functionalization of nematic topological defects. Experimental realizations however question the complex behaviour of solid particles and defects embedded in such a nematic spherical shell. In order to address the related topological and geometrical issues, we have studied micrometer-sized silica beads trapped in nematic shells. We underline the mechanisms that strongly modify the texture of the simple (particle-free) shells when colloidal particles are embedded. Finally, we show how the coupling between capillarity and nematic elasticity offers new ways to control the valence and directionality of shells.
引用
收藏
页码:6911 / 6920
页数:10
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