Effect of Electrodeposition Potential on Surface Free Energy and Supercapacitance of MnO2 Thin Films

被引:26
作者
Relekar, B. P. [1 ,2 ]
Mahadik, S. A. [4 ]
Jadhav, S. T. [1 ]
Patil, A. S. [1 ]
Koli, R. R. [1 ]
Lohar, G. M. [3 ]
Fulari, V. J. [1 ]
机构
[1] Shivaji Univ, Dept Phys, Holog & Mat Res Lab, Kolhapur 416004, MH, India
[2] Yashwantrao Chavan Coll Sci, Karad, India
[3] Lal Bahadur Shastri Coll Arts Sci & Commerce, Satara 415002, India
[4] Univ Seoul, Dept Mat Sci & Engn, Seoul 130743, South Korea
关键词
Electrodeposition; supercapacitance; surface free energy; PHOTOELECTROCHEMICAL CELL APPLICATION; LITHIUM ION BATTERIES; MODIFIED SILAR METHOD; MANGANESE-DIOXIDE; ELECTROCHEMICAL PROPERTIES; HIERARCHICAL MNO2; HIGH-CAPACITY; STORAGE; HYBRID; OXIDE;
D O I
10.1007/s11664-018-6109-9
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The effect of anodic deposition potential on the supercapacitance of manganese dioxide (MnO2) and effect of surface free energy (SFE) on the supercapacitance are discussed. MnO2 thin films have been synthesized using a potentiostatic electrodeposition method. Their structure, morphology, wettability, electrochemical properties and supercapacitance are discussed. The observed specific capacitance (C-s) of MnO2 thin films is 127 F/g for the deposition potential at 1.20 V/Ag/AgCl. These films also show better stability for over 1000 cycles. The porous MnO2 thin films lead to high SFE and a corresponding high value of specific capacitance.
引用
收藏
页码:2731 / 2738
页数:8
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