Ultraporous palladium on flexible graphene-coated carbon fiber paper as high-performance electro-catalysts for the electro-oxidation of ethanol

被引：62

作者：

Sawangphruk, Montree ^{[1
,2
]}

Krittayavathananon, Atiweena ^{[1
]}

Chinwipas, Natee ^{[1
]}

机构：

[1] Kasetsart Univ, Natl Ctr Excellence Petr Petrochem & Adv Mat, Dept Chem Engn, Fac Engn, Bangkok 10900, Thailand

[2] Kasetsart Univ, Ctr Adv Studies Nanotechnol & Its Applicat Chem, Bangkok 10900, Thailand

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 04期

关键词：

ENHANCED ELECTROCATALYTIC ACTIVITY; ALKALINE MEDIA; FUEL-CELLS; METHANOL ELECTROOXIDATION; OXIDATION REACTION; SMALL MOLECULES; FORMIC-ACID; PD; NI; ELECTRODEPOSITION;

D O I：

10.1039/c2ta00659f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For palladium nanocatalysts (PdNCs) to be used as a successfully high-performance direct ethanol fuel cell anode material, improvements in electro-catalytic activity and stability are needed. Here we show an excellent controllable electrodeposition method for fabricating the ultraporous structure of PdNCs. Ultraporous PdNCs were coated on three different carbon materials: flexible carbon fiber paper (CFP), and CFP modified with either graphene oxide (GO) or reduced graphene oxide (rGO) nanosheets. The as-fabricated electrode of PdNCs/rGO/CFP exhibits higher catalytic activity toward the electro-oxidation of ethanol in alkaline media, more excellent poisoning tolerance to carbonaceous species, and higher stability than other electrodes.

引用

页码：1030 / 1034

页数：5

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