Liquid-liquid equilibrium of ternary systems of cyclohexane plus (benzene, plus toluene, plus ethylbenzene, or plus o-xylene)+4-methyl-N-butyl pyridinium tetrafluoroborate ionic liquid at 303.15 K

被引:81
|
作者
Abu-Eishah, Samir I. [1 ]
Dowaidar, Ali M. [1 ]
机构
[1] UAE Univ, Dept Chem & Petr Engn, Al Ain, U Arab Emirates
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D O I
10.1021/je7007268
中图分类号
O414.1 [热力学];
学科分类号
摘要
Liquid-liquid equilibrium data are critical for designing the extraction equipment or calculating the thermodynamic limit of a given separation. In this work, the LLE data were measured for the cyclohexane + (benzene, + toluene, + ethylbenzene, or + o-xylene) + 4-methyl-N-butyl pyridinium tetrafluoroborate ([bmpy]BF4) systems at 303.15 K under atmospheric pressure. The consistency of the measured LLE data was tested using the Othmer-Tobias correlation and the root-mean-square deviation (rmsd) in the mass fraction of [bmpy]BF4 in the lower phase and the average value of the absolute difference (AAD) between experimental mass fraction of cyclohexane in the upper phase and that calculated using the Othmer-Tobias correlation.
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页码:1708 / 1712
页数:5
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