Unconventional Reactivity of Imidazolylidene Pyridylidene Ligands in Iridium(III) and Rhodium(III) Complexes

被引：41

作者：

Segarra, Candela ^{[1
]}

Mas-Marza, Elena ^{[1
]}

Benitez, Miriam ^{[1
]}

Mata, Jose A. ^{[1
]}

Peris, Eduardo ^{[1
]}

机构：

[1] Univ Jaume 1, Dpto Quim Inorgan & Organ, Castellon de La Plana 12071, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 43期

关键词：

C?C coupling; cyclopentadienyl ligands; heterocycles; iridium; rhodium; RING-METHYL ACTIVATION; C-H ACTIVATION; PENTAMETHYLCYCLOPENTADIENYL COMPLEXES; CHELATING LIGAND; NHC LIGANDS; CARBENES; OXIDATION; ALKOXYLATION; HYDROLYSIS; INSERTION;

D O I：

10.1002/anie.201206175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Expect the unexpected: The reactions of a series of imidazolium pyridinium salts with [{IrCp*Cl 2} 2] and [{RhCp*Cl 2} 2] afford a series of complexes. Together with the expected bis(NHC) complexes, some species resulting from C-C coupling between the pyridylidene and Cp* ligands were observed (see figure; Cp*=pentamethylcyclopentadienyl). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10841 / 10845

页数：5

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