{W48} Ring Opening: Fe16-Containing, Ln4-Stabilized 49-Tungsto-8-Phosphate Open Wheel [Fe16O2(OH)23(H2O)9(P8W49O189)Ln4(H2O)20]11-

被引：68

作者：

Ismail, Amal H. ^{[1
]}

Bassil, Bassem S. ^{[1
]}

Yassin, Ghada H. ^{[1
]}

Keita, Bineta ^{[2
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany

[2] Univ Paris 11, Lab Chim Phys, UMR 8000, CNRS,Equipe Electrochim & Photoelectrochim, F-91405 Orsay, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 20期

关键词：

electrochemistry; nanocluster; polyoxometalates; self-assembly; SHAPED CU-20 TUNGSTOPHOSPHATE; HEXAVACANT TUNGSTOPHOSPHATE; COORDINATION CHEMISTRY; CROWN HETEROPOLYANION; WATER-PURIFICATION; NUCLEATION PROCESS; POLYOXOMETALATE; IONS; POLYOXOTUNGSTATE; PHOTOCATALYSIS;

D O I：

10.1002/chem.201200963

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Wheely: For the first time and very unexpectedly, a rupture of the very stable {P 8W 48} wheel was observed in aqueous solution at pH 4 and 80 °C in the presence of Fe III, Eu III/Gd III, and H 2O 2. This inorganic ring opening is unprecedented in polyoxometalate chemistry. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6163 / 6166

页数：4

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