{W48} Ring Opening: Fe16-Containing, Ln4-Stabilized 49-Tungsto-8-Phosphate Open Wheel [Fe16O2(OH)23(H2O)9(P8W49O189)Ln4(H2O)20]11-

被引：68
作者：
Ismail, Amal H. [1 ]
Bassil, Bassem S. [1 ]
Yassin, Ghada H. [1 ]
Keita, Bineta [2 ]
Kortz, Ulrich [1 ]
机构：
[1] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany
[2] Univ Paris 11, Lab Chim Phys, UMR 8000, CNRS,Equipe Electrochim & Photoelectrochim, F-91405 Orsay, France
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 20期
关键词：
electrochemistry; nanocluster; polyoxometalates; self-assembly; SHAPED CU-20 TUNGSTOPHOSPHATE; HEXAVACANT TUNGSTOPHOSPHATE; COORDINATION CHEMISTRY; CROWN HETEROPOLYANION; WATER-PURIFICATION; NUCLEATION PROCESS; POLYOXOMETALATE; IONS; POLYOXOTUNGSTATE; PHOTOCATALYSIS;
D O I：
10.1002/chem.201200963
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Wheely: For the first time and very unexpectedly, a rupture of the very stable {P 8W 48} wheel was observed in aqueous solution at pH 4 and 80 °C in the presence of Fe III, Eu III/Gd III, and H 2O 2. This inorganic ring opening is unprecedented in polyoxometalate chemistry. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6163 / 6166
页数：4
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