共 244 条
On the Role of Metals in Nitrogen-Doped Carbon Electrocatalysts for Oxygen Reduction
被引:613
作者:

Masa, Justus
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h-index: 0
机构:
Ruhr Univ Bochum, Analyt Chem & Ctr Electrochem Sci, D-44780 Bochum, Germany Ruhr Univ Bochum, Analyt Chem & Ctr Electrochem Sci, D-44780 Bochum, Germany

Xia, Wei
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h-index: 0
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Ruhr Univ Bochum, Lab Ind Chem, D-44780 Bochum, Germany Ruhr Univ Bochum, Analyt Chem & Ctr Electrochem Sci, D-44780 Bochum, Germany

Muhler, Martin
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h-index: 0
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Ruhr Univ Bochum, Lab Ind Chem, D-44780 Bochum, Germany Ruhr Univ Bochum, Analyt Chem & Ctr Electrochem Sci, D-44780 Bochum, Germany

Schuhmann, Wolfgang
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h-index: 0
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Ruhr Univ Bochum, Analyt Chem & Ctr Electrochem Sci, D-44780 Bochum, Germany Ruhr Univ Bochum, Analyt Chem & Ctr Electrochem Sci, D-44780 Bochum, Germany
机构:
[1] Ruhr Univ Bochum, Analyt Chem & Ctr Electrochem Sci, D-44780 Bochum, Germany
[2] Ruhr Univ Bochum, Lab Ind Chem, D-44780 Bochum, Germany
关键词:
carbon;
doping;
electrocatalysis;
metal-free catalysts;
oxygen reduction;
ANION-EXCHANGE MEMBRANES;
ELECTROLYTE FUEL-CELLS;
FE-BASED CATALYSTS;
HIGH-AREA CARBON;
HIGHLY-ACTIVE ELECTROCATALYST;
ALKALINE POLYMER ELECTROLYTE;
ONE-POT SYNTHESIS;
O-2;
REDUCTION;
TRANSITION-METAL;
RECENT PROGRESS;
D O I:
10.1002/anie.201500569
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The notion of metal-free catalysts is used to refer to carbon materials modified with nonmetallic elements. However, some claimed metalfree catalysts are prepared using metal-containing precursors. It is highly contested that metal residues in nitrogen-doped carbon (NC) catalysts play a crucial role in the oxygen reduction reaction (ORR). In an attempt to reconcile divergent views, a definition for truly metal-free catalysts is proposed and the differences between NC and M-Nx/C catalysts are discussed. Metal impurities at levels usually undetectable by techniques such as XPS, XRD, and EDX significantly promote the ORR. Poisoning tests to mask the metal ions reveal the involvement of metal residues as active sites or as modifiers of the electronic structure of the active sites in NC. The unique merits of both M-Nx/C and NC catalysts are discussed to inspire the development of more advanced nonprecious-metal catalysts for the ORR.
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页码:10102 / 10120
页数:19
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- [111] Nitrogen-doped graphdiyne as a metal-free catalyst for high-performance oxygen reduction reactions[J]. NANOSCALE, 2014, 6 (19) : 11336 - 11343Liu, Rongji论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China Univ Chinese Acad Sci, Beijing 100049, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaLiu, Huibiao论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, BNLMS, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaLi, Yuliang论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, BNLMS, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaYi, Yuanping论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, BNLMS, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaShang, Xinke论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China Univ Chinese Acad Sci, Beijing 100049, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaZhang, Shuangshuang论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China Univ Chinese Acad Sci, Beijing 100049, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaYu, Xuelian论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaZhang, Suojiang论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaCao, Hongbin论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R ChinaZhang, Guangjin论文数: 0 引用数: 0 h-index: 0机构: Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
- [112] Nitrogen-Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (14) : 2565 - 2569Liu, Ruili论文数: 0 引用数: 0 h-index: 0机构: Max Planck Inst Polymer Res, D-55128 Mainz, Germany Max Planck Inst Polymer Res, D-55128 Mainz, GermanyWu, Dongqing论文数: 0 引用数: 0 h-index: 0机构: Max Planck Inst Polymer Res, D-55128 Mainz, Germany Max Planck Inst Polymer Res, D-55128 Mainz, GermanyFeng, Xinliang论文数: 0 引用数: 0 h-index: 0机构: Max Planck Inst Polymer Res, D-55128 Mainz, Germany Max Planck Inst Polymer Res, D-55128 Mainz, GermanyMuellen, Klaus论文数: 0 引用数: 0 h-index: 0机构: Max Planck Inst Polymer Res, D-55128 Mainz, Germany Max Planck Inst Polymer Res, D-55128 Mainz, Germany
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