Thermodynamic studies of dynamic metal ligands with copper(II), cobalt(II), zinc(II) and nickel(II)

被引：4

作者：

Long, S. Reid ^{[1
]}

Lin, Chung-Yon ^{[1
]}

Anslyn, Eric V. ^{[1
]}

机构：

[1] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2017年 / 70卷 / 01期

基金：

美国国家科学基金会;

关键词：

Dynamic chemistry; Click chemistry; ITC; Thermodynamics; CHIRAL SECONDARY ALCOHOLS; ENANTIOMERIC EXCESS; CYCLOADDITION; CHEMISTRY;

D O I：

10.1080/00958972.2016.1262949

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The self-assembly of unsymmetrical metal ligands from simpler components circumvents complex synthetic approaches. We show herein how a recently developed three-component assembly to create tripicolylamine-like ligands can be extended to the use of azides rather than pyridines. Substituent effects, metal dependence, and reversibility of the assembly are explored. Further, we show that the extent of assembly directly correlates with the differential binding of the templating metals between dipicolylamine-like and tripicolyamine-like ligands.

引用

页码：1 / 9

页数：9

共 14 条

[1] The coordination chemistry of tripodal tetraamine ligands [J].