The elusive tripodal tris(2-pyridyl)borate ligand: a strongly coordinating tetraarylborate

被引：41

作者：

Cui, Chengzhong ^{[1
]}

Lalancette, Roger A. ^{[1
]}

Jaekle, Frieder ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 55期

基金：

美国国家科学基金会;

关键词：

ELECTRONIC SPIN-STATE; SCORPIONATE; POLYMERIZATION; ACTIVATION; COMPLEXES;

D O I：

10.1039/c2cc33059h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris(2-pyridyl)borates are introduced as a new robust and tunable "scorpionate"-type ligand family. A facile synthesis of this hitherto unknown ligand and its complexation to Fe(II) are described; the optical and electrochemical properties of the resulting iron complex are compared to complexes derived from tris(pyrazolyl) borate, tris(2-pyridyl) aluminate, and corresponding charge-neutral ligands.

引用

页码：6930 / 6932

页数：3

共 30 条

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